Compact batteries enhanced by spontaneous silver matrix formations

Optical images of the non-discharged cathode, showing key differences in the lithium-facing and steel-facing sides. Credit: Image courtesy of Brookhaven National Laboratory

In a promising lithium-based battery, the formation of a highly conductive silver matrix transforms a material otherwise plagued by low conductivity. To optimize these multi-metallic batteries -- and enhance the flow of electricity -- scientists needed a way to see where, when, and how these silver, nanoscale "bridges" emerge.

Now, researchers from the U.S. Department of Energy's Brookhaven National Laboratory and Stony Brook University have used x-rays to map this changing atomic architecture and revealed its link to the battery's rate of discharge. The study -- published online Jan. 8, 2015, in the journal Science -- shows that a slow discharge rate early in the battery's life creates a more uniform and expansive conductive network, suggesting new design approaches and optimization techniques.

"Armed with this insight into battery cathode discharge processes, we can target new materials designed to address critical battery issues associated with power and efficiency," said study coauthor Esther Takeuchi, a SUNY Distinguished Professor at Stony Brook University and Chief Scientist in Brookhaven Lab's Basic Energy Sciences Directorate.

The scientists used bright x-ray beams at Brookhaven Lab's National Synchrotron Light Source (NSLS) -- a DOE Office of Science User Facility -- to probe lithium batteries with silver vanadium diphosphate (Ag2VP2O8) electrodes. This promising cathode material, which may be useful in implantable medical devices, exhibits the high stability, high voltage, and spontaneous matrix formation central to the research.

"The experimental work -- in particular the in-situ x-ray diffraction in batteries totally encased in stainless steel -- should prove useful for industry as it can penetrate prototype and production-level batteries to track their structural evolution during operation," Takeuchi said.

Into the matrix

As these single-use batteries -- synthesized and assembled by Stony Brook graduate student David Bock -- discharge, the lithium ions stored in the anode travel to the cathode, displacing silver ions along the way. The displaced silver then combines with free electrons and unused cathode material to form the conductive silver metal matrix, acting as a conduit for the otherwise impeded electron flow.

"To visualize the cathode processes within the battery and watch the silver network take shape, we needed a very precise system with huseigh-intensity x-rays capable of penetrating a steel battery casing," said study coauthor and Stony Brook University Research Associate Professor Amy Marschilok. "So we turned to NSLS."

Energy dispersive x-ray diffraction (EDXRD) at NSLS provided this real-time -- in situ -- visualization data. In EDXRD, intense beams of x-rays passed through the sample, losing energy as the battery structure bent the beams. Each set of detected beam angles, like time-lapse images, revealed the shifting chemistry as a function of battery discharge.

"The silver forms in particles spanning less than 10 nanometers, and the diffraction patterns can be both dense and faint," said Brookhaven Lab scientist Zhong Zhong, who performed the critical alignment for the x-ray experiments at NSLS.

Once the data was collected, Brookhaven Lab postdoctoral researcher and study coauthor Kevin Kirshenbaum led the data analysis effort.

"This kind of analysis and interpretation requires considerable time and expertise, but the results can be stunning," Kirshenbaum said.

Surprises written in silver

In most batteries, the speed of lithium-ion diffusion determines the rate of discharge, a key factor in overall performance and efficiency. The material closest to the lithium anode would ordinarily discharge first, as the ions have a shorter distance to travel. In a surprising discovery, the researchers found that the material farthest from the anode and nearest the coin cell surface discharged first in the battery.

"This is because the non-discharged cathode material is a very poor electric conductor, so the resistance for lithium ion diffusion is less than for electron flow," said coauthor and SUNY Distinguished Teaching Professor Kenneth Takeuchi. "This highlights a uniquely efficient aspect of in situ silver matrix formation: The silver matrix forms primarily where needed, which is more efficient than using conductive additives."

The in situ diffraction data was combined with two techniques applied after operation: x-ray absorption spectroscopy (XAS) and angle-resolved x-ray diffraction (XRD).

Spectroscopy can reveal exact chemistry because each element absorbs and emits light uniquely, but the x-rays used for XAS cannot penetrate the battery casing. So after each step in the discharge, the researchers removed the cathode and ground it into a powder to measure the average elemental composition. Chia-Ying Lee of the University at Buffalo prepared the reduced cathode materials for the initial ex situ measurements.

"These techniques provide complementary data: the in situ diffraction shows where the silver is formed within the cathode, while the spectroscopy shows more precisely how much silver was formed," Esther Takeuchi said.

Brighter lights and better batteries

NSLS ended its 32-year experimental run in September 2014, but its powerful successor is 

already taking data at Brookhaven Lab. The National Synchrotron Light Source II (NSLS-II) provides beams 10,000 times brighter than NSLS, and in situ energy research is a major part of its mission. NSLS-II, also a DOE Office of Science User Facility, will soon welcome users from industry, academia, and other national labs.

"We are currently working on other materials that form conductive networks and hope to study them as functioning cells," Takeuchi said. "The brighter beams and greater spatial resolution of NSLS-II will be a great tool in studying other cathodes and pushing this technology forward."

This research was funded by the U.S. Department of Energy's Office of Science.

Source: Brookhaven National Laboratory

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Switching to vehicles powered by electricity from renewables could save lives

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. Credit: © Dmitry Vereshchagin / Fotolia

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. This finding comes from a new life cycle analysis of conventional and alternative vehicles and their air pollution-related public health impacts, published Monday, Dec. 15, 2014, in the Proceedings of the National Academy of Sciences.

The study also shows that switching to vehicles powered by electricity made using natural gas yields large health benefits. Conversely, vehicles running on corn ethanol or vehicles powered by coal-based or "grid average" electricity are worse for health; switching from gasoline to those fuels would increase the number of resulting deaths due to air pollution by 80 percent or more.

"These findings demonstrate the importance of clean electricity, such as from natural gas or renewables, in substantially reducing the negative health impacts of transportation," said Chris Tessum, co-author on the study and a researcher in the Department of Civil, Environmental, and Geo- Engineering in the University of Minnesota's College of Science and Engineering.

The University of Minnesota team estimated how concentrations of two important pollutants -- particulate matter and ground-level ozone -- change as a result of using various options for powering vehicles. Air pollution is the largest environmental health hazard in the U.S., in total killing more than 100,000 people per year. Air pollution increases rates of heart attack, stroke, and respiratory disease.

The authors looked at liquid biofuels, diesel, compressed natural gas, and electricity from a range of conventional and renewable sources. Their analysis included not only the pollution from vehicles, but also emissions generated during production of the fuels or electricity that power them. With ethanol, for example, air pollution is released from tractors on farms, from soils after fertilizers are applied, and to supply the energy for fermenting and distilling corn into ethanol.

"Our work highlights the importance of looking at the full life cycle of energy production and use, not just at what comes out of tailpipes," said Bioproducts and Biosystems Engineering Assistant Professor Jason Hill, co-author of the study. "We greatly underestimate transportation's impacts on air quality if we ignore the upstream emissions from producing fuels or electricity."

The researchers also point out that whereas recent studies on life cycle environmental impacts of transportation have focused mainly on greenhouse gas emissions, it is also important to consider air pollution and health. Their study provides a unique look at where life cycle emissions occur, how they move in the environment, and where people breathe that pollution. Their results provide unprecedented detail on the air quality-related health impacts of transportation fuel production and use.

"Air pollution has enormous health impacts, including increasing death rates across the U.S.," said Civil, Environmental and Geo- Engineering Associate Professor Julian Marshall, co-author on this study. "This study provides valuable new information on how some transportation options would improve or worsen those health impacts."

Source: University of Minnesota

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Deepwater Horizon spill: Much of the oil at bottom of the sea

Controlled burning of surface oil slicks during the Deepwater Horizon event.
Credit: David Valentine

Due to the environmental disaster's unprecedented scope, assessing the damage caused by the 2010 Deepwater Horizon spill in the Gulf of Mexico has been a challenge. One unsolved puzzle is the location of 2 million barrels of submerged oil thought to be trapped in the deep ocean.

UC Santa Barbara's David Valentine and colleagues from the Woods Hole Oceanographic Institute (WHOI) and UC Irvine have been able to describe the path the oil followed to create a footprint on the deep ocean floor. The findings appear today in the Proceedings of the National Academy of Sciences.

For this study, the scientists used data from the Natural Resource Damage Assessment process conducted by the National Oceanic and Atmospheric Administration. The United States government estimates the Macondo well's total discharge -- from the spill in April 2010 until the well was capped that July -- to be 5 million barrels.

By analyzing data from more than 3,000 samples collected at 534 locations over 12 expeditions, they identified a 1,250-square-mile patch of the deep sea floor upon which 2 to 16 percent of the discharged oil was deposited. The fallout of oil to the sea floor created thin deposits most intensive to the southwest of the Macondo well. The oil was most concentrated within the top half inch of the sea floor and was patchy even at the scale of a few feet.

The investigation focused primarily on hopane, a nonreactive hydrocarbon that served as a proxy for the discharged oil. Researchers analyzed the spatial distribution of hopane in the northern Gulf of Mexico and found it was most concentrated in a thin layer at the sea floor within 25 miles of the ruptured well, clearly implicating Deepwater Horizon as the source.

"Based on the evidence, our findings suggest that these deposits come from Macondo oil that was first suspended in the deep ocean and then settled to the sea floor without ever reaching the ocean surface," said Valentine, a professor of earth science and biology at UCSB. "The pattern is like a shadow of the tiny oil droplets that were initially trapped at ocean depths around 3,500 feet and pushed around by the deep currents. Some combination of chemistry, biology and physics ultimately caused those droplets to rain down another 1,000 feet to rest on the sea floor."

Valentine and his colleagues were able to identify hotspots of oil fallout in close proximity to damaged deep-sea corals. According to the researchers, this data supports the previously disputed finding that these corals were damaged by the Deepwater Horizon spill.

"The evidence is becoming clear that oily particles were raining down around these deep sea corals, which provides a compelling explanation for the injury they suffered," said Valentine. "The pattern of contamination we observe is fully consistent with the Deepwater Horizon event but not with natural seeps -- the suggested alternative."

While the study examined a specified area, the scientists argue that the observed oil represents a minimum value. They purport that oil deposition likely occurred outside the study area but so far has largely evaded detection because of its patchiness.

"This analysis provides us with, for the first time, some closure on the question 'Where did the oil go and how?' " said Don Rice, program director in the National Science Foundation's Division of Ocean Sciences. "It also alerts us that this knowledge remains largely provisional until we can fully account for the remaining 70 percent."

"These findings should be useful for assessing the damage caused by the Deepwater Horizon spill as well as planning future studies to further define the extent and nature of the contamination," Valentine concluded. "Our work can also help to assess the fate of reactive hydrocarbons, test models of oil's behavior in the ocean and plan for future spills."

Co-authors are G. Burch Fisher and Sarah C. Bagby, postdoctoral researchers in the Valentine Lab at UCSB; Robert K. Nelson, Christopher M. Reddy and Sean P. Sylva of WHOI; and Mary A. Woo of UC Irvine. The research was funded by the National Science Foundation.

Source:  University of California - Santa Barbara

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New conversion process turns biomass 'waste' into lucrative chemical products

Purdue's R.B. Wetherill Professor of Chemistry, holds a small vial containing results of a new catalytic process that can convert the lignin in wood into high-value chemical products for use in fragrances and flavoring.
Credit: Purdue University photo/Mark Simons

A new catalytic process is able to convert what was once considered biomass waste into lucrative chemical products that can be used in fragrances, flavorings or to create high-octane fuel for racecars and jets.

A team of researchers from Purdue University's Center for Direct Catalytic Conversion of Biomass to Biofuels, or C3Bio, has developed a process that uses a chemical catalyst and heat to spur reactions that convert lignin into valuable chemical commodities. Lignin is a tough and highly complex molecule that gives the plant cell wall its rigid structure.

Mahdi Abu-Omar, the R.B. Wetherill Professor of Chemistry and Professor of Chemical Engineering and associate director of C3Bio, led the team.

"We are able to take lignin -- which most biorefineries consider waste to be burned for its heat -- and turn it into high-value molecules that have applications in fragrance, flavoring and high-octane jet fuels," Abu-Omar said. "We can do this while simultaneously producing from the biomass lignin-free cellulose, which is the basis of ethanol and other liquid fuels. We do all of this in a one-step process."

Plant biomass is made up primarily of lignin and cellulose, a long chain of sugar molecules that is the bulk material of plant cell walls. In standard production of ethanol, enzymes are used to break down the biomass and release sugars. Yeast then feast on the sugars and create ethanol.

Lignin acts as a physical barrier that makes it difficult to extract sugars from biomass and acts as a chemical barrier that poisons the enzymes. Many refining processes include harsh pretreatment steps to break down and remove lignin, he said.

"Lignin is far more than just a tough barrier preventing us from getting the good stuff out of biomass, and we need to look at the problem differently," Abu-Omar said. "While lignin accounts for approximately 25 percent of the biomass by weight, it accounts for approximately 37 percent of the carbon in biomass. As a carbon source lignin can be very valuable, we just need a way to tap into it without jeopardizing the sugars we need for biofuels."

The Purdue team developed a process that starts with untreated chipped and milled wood from sustainable poplar, eucalyptus or birch trees. A catalyst is added to initiate and speed the desired chemical reactions, but is not consumed by them and can be recycled and used again. A solvent is added to the mix to help dissolve and loosen up the materials. The mixture is contained in a pressurized reactor and heated for several hours. The process breaks up the lignin molecules and results in lignin-free cellulose and a liquid stream that contains two additional chemical products, Abu-Omar said.

The liquid stream contains the solvent, which is easily evaporated and recycled, and two phenols, a class of aromatic hydrocarbon compounds used in perfumes and flavorings. A commonly used artificial vanilla flavoring is currently produced using a phenol that comes from petroleum, he said.

The team also developed an additional process that uses another catalyst to convert the two phenol products into high-octane hydrocarbon fuel suitable for use as drop-in gasoline. The fuel produced has a research octane rating greater than100, whereas the average gas we put into our cars has an octane rating in the eighties, he said.

The processes and resulting products are detailed in a paper published online in the Royal Society of Chemistry journal Green Chemistry. The U.S. Department of Energy funded the research.

In addition to Abu-Omar, co-authors include Trenton Parsell, a visiting scholar in the Department of Chemistry; chemical engineering graduate students Sara Yohe, John Degenstein, Emre Gencer, and Harshavardhan Choudhari; chemistry graduate students Ian Klein, Tiffany Jarrell, and Matt Hurt; agricultural and biological engineering graduate student Barron Hewetson; Jeong Im Kim, associate research scientist in biochemistry; Basudeb Saha, associate research scientist in chemistry; Richard Meilan, professor of forestry and natural reserouces; Nathan Mosier, associate professor of agricultural and biological engineering; Fabio Ribeiro, the R. Norris and Eleanor Shreve Professor of Chemical Engineering; W. Nicholas Delgass, the Maxine S. Nichols Emeritus Professor of Chemical Engineering; Clint Chapple, the head and distinguished professor of biochemistry; Hilkka I. Kenttamaa, professor of chemistry; and Rakesh Agrawal, the Winthrop E. Stone Distinguished Professor of Chemical Engineering.

The catalyst is expensive, and the team plans to further study efficient ways to recycle it, along with ways to scale up the entire process, Abu-Omar said.

"A biorefinery that focuses not only on ethanol, but on other products that can be made from the biomass is more efficient and profitable overall," he said. "It is possible that lignin could turn out to be more valuable than cellulose and could subsidize the production of ethanol from sustainable biomass."

The U.S. Department of Energy-funded C3Bio center is an Energy Frontier Research Center. It is part of Discovery Park's Energy Center and the Bindley Bioscience Center at Purdue.

Purdue Research Foundation has filed patent applications and launched a startup company, Spero Energy, which was founded by Abu-Omar.

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Source:  Purdue University

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Storing hydrogen underground could boost transportation, energy security

Salt caverns such as the one depicted here could provide a low-cost solution for the geologic storage of hydrogen. The colors in the illustration represent depth, with blue as the deepest part of the cavern and red the most shallow.
Credit: Sandia National Laboratories

Large-scale storage of low-pressure, gaseous hydrogen in salt caverns and other underground sites for transportation fuel and grid-scale energy applications offers several advantages over above-ground storage, says a recent Sandia National Laboratories study sponsored by the Department of Energy's Fuel Cell Technologies Office.

Geologic storage of hydrogen gas could make it possible to produce and distribute large quantities of hydrogen fuel for the growing fuel cell electric vehicle market, the researchers concluded.

Geologic storage solutions can service a number of key hydrogen markets since "costs are more influenced by the geology available rather than the size of the hydrogen market demand," said Sandia's Anna Snider Lord, the study's principal investigator.

The work, Lord said, could provide a roadmap for further research and demonstration activities, such as an examination of environmental issues and geologic formations in major metropolitan areas that can hold gas. Researchers could then determine whether hydrogen gas mixes with residual gas or oil, reacts with minerals in the surrounding rock or poses any environmental concerns.

Storage seen as key to realizing hydrogen's market growth

Should the market demands for hydrogen fuel increase with the introduction of fuel cell electric vehicles, the U.S. will need to produce and store large amounts of cost-effective hydrogen from domestic energy sources, such as natural gas, solar and wind, said Daniel Dedrick, Sandia hydrogen program manager.

As Toyota, General Motors, Hyundai and others move ahead with plans to develop and sell or lease hydrogen fuel cell electric vehicles, practical storage of hydrogen fuel at large scale is nessesary to enable widespread hydrogen-powered transportation infrastructure. Such storage options, Dedrick said, are needed to realize the full potential of hydrogen for transportation.

Additionally, installation of electrolyzer systems on electrical grids for power-to-gas applications, which integrate renewable energy, grid services and energy storage will require large-capacity, cost-effective hydrogen storage.

Storage above ground requires tanks, which cost three to five times more than geologic storage, Lord said. In addition to cost savings, underground storage of hydrogen gas offers advantages in volume. "Above-ground tanks can't even begin to match the amount of hydrogen gas that can be stored underground," she said.
The massive quantities of hydrogen that is stored in geologic features can subsequently be distributed as a high-pressure gas or liquid to supply hydrogen fuel markets.

Model helps identify the most favorable storage locations
While geologic storage may prove to be a viable option, several issues need to be explored, said Lord, including permeability of various geologic formations.

A geologist in Sandia's geotechnology and engineering group, Lord for years has been involved in the geologic storage of the U.S. Strategic Petroleum Reserve, the world's largest emergency supply of crude oil.

For her study on geologic storage, Lord and her colleagues analyzed and reworked the geologic storage module of Argonne National Laboratory's Hydrogen Delivery Scenario Analysis Model. To help refine the model, Lord studied storing hydrogen in salt caverns to meet peak summer driving demand for four cities: Los Angeles, Houston, Pittsburgh and Detroit.

She determined that 10 percent above the average daily demand for 120 days should be stored. She then modeled how much hydrogen each city would need if hydrogen met 10, 25 and 100 percent of its driving fuel needs.

Los Angeles has three times the population of Detroit and more than six and a half times the population of Pittsburgh, but the nearest salt formations are in Arizona, so Lord included the cost of getting the stored hydrogen from Arizona to Los Angeles.

Even so, Los Angeles' modeled costs are significantly less than those for Detroit and Pittsburgh. Salt formations in Arizona are thicker than those for Detroit and Pittsburgh, with larger and fewer caverns. Houston has the best conditions of the four cities because the Gulf Coast offers large, deep salt formations.

To examine the cost of geologic hydrogen storage, Lord started by selecting geologic formations that currently store natural gas. Working with Sandia economist Peter Kobos, Lord analyzed costs to store hydrogen gas in depleted oil and gas reservoirs, aquifers, salt caverns and hard rock caverns.

Their paper, "Geologic storage of hydrogen: Scaling up to meet city transportation demands," was published in the International Journal of Hydrogen Energy.

A geologic solution for peak period storage
Other fuels are already stored geologically. Oil from the Strategic Petroleum Reserve, for example, is held in large man-made caverns along the Gulf Coast. Natural gas is stored in more than 400 geologic sites to meet winter heating demands.

Lord envisions that excess hydrogen produced throughout the year could be brought to geologic storage sites and then piped to cities during the summer, when the demand for driving fuels peaks.

Depleted oil and gas reservoirs and aquifers initially seem the most economically attractive options, she said. "Just looking at numbers, because they can hold such a larger volume relative to any cavern you create, they look cheaper," she said.

But hydrogen gas is a challenging substance to store. "Because it's a smaller molecule than methane, for example, it has the potential to leak easier and move faster through the rock," Lord said.

Depleted oil and gas reservoirs and aquifers could leak hydrogen, and cycling -- filling a storage site, pulling hydrogen out for use and refilling the site -- can't be done more than once or twice a year to preserve the integrity of the rock formation, Lord said.
With a salt cavern or hard rock cavern, "there are no permeability issues, there's really no way anything can leak," she said. "You can bring more product in and out, and that will, in the long run, decrease your costs."

Hard rock caverns are relatively unproven; only one site holds natural gas. But salt caverns, which are created 1,000 to 6,000 feet below ground by drilling wells in salt formations, pumping in undersaturated water to dissolve the salt, then pumping out the resulting brine, are used more extensively and already store hydrogen on a limited scale, Lord said.

Future challenges

Lord said her work could lead to demonstration projects to further cement the viability of underground hydrogen storage. Salt caverns are the logical choice for a pilot project due to their proven ability to hold hydrogen, she said. Environmental concerns such as contamination could also be further analyzed.

However, salt formations are limited. None exist in the Pacific Northwest, much of the East Coast and much of the South, except for the Gulf Coast area. Other options are needed for development of a nationwide hydrogen storage system.

Lord's work adds to Sandia's capabilities and decades of experience in hydrogen and fuel cells systems. Sandia leads a number of other hydrogen research efforts, including the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) project co-led by the National Renewable Energy Laboratory (NREL), a maritime fuel cell demonstration, a development project focused on hydrogen-powered forklifts and a recent study of how many California gas stations can safely store and dispense hydrogen.

Source: Sandia National Laboratories

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Is natural gas a 'bridge' to a hotter future?

This image shows a natural gas plant in Moss Landing, California. Credit: Carnegie President Matthew Scott

Natural gas power plants produce substantial amounts of gases that lead to global warming. Replacing old coal-fired power plants with new natural gas plants could cause climate damage to increase over the next decades, unless their methane leakage rates are very low and the new power plants are very efficient.

These are the principal findings of new research from Carnegie's Ken Caldeira and Xiaochun Zhang, and Nathan Myhrvold of Intellectual Ventures that compares the temperature increases caused by different kinds of coal and natural gas power plants. Their work is published in Environmental Research Letters.

There is an ongoing debate among people concerned with power plants and the future of energy policy and greenhouse gas emissions. Does it makes sense to replace old coal-fired power plants with new natural gas power plants today, as a bridge to a longer-term transition toward near zero-emission energy generation technologies such as solar, wind, or nuclear power? A key issue in considering the decision has been the potential climate effects of natural gas versus coal. Studies have yielded different results by focusing on power plants with different characteristics and using different definitions of what it means to be "better" for climate.

Carnegie's Caldeira and Zhang, along with Myhrvold, aimed to identify the key factors that are responsible for most of the difference in greenhouse gas emissions between individual gas and coal plants. The key factors, they found, are power plant efficiency and, in the case of natural gas plants, methane leakage during the supply process. They used these factors to derive a simple model for resulting temperature change caused by the carbon dioxide and methane released by a particular plant.

The team chose a simple and understandable way to compare climate effects of different types of power plants. They predicted how much global warming would be produced by different kinds of power plants during and after their period of operation.

They found that because natural gas plants are overall more efficient than coal plants, producing more energy per unit of carbon, they could cause less warming in the long term. However, it all depends on the amount of methane leakage that occurs. Natural gas plants that leak a substantial amount of methane during their supply process can produce more warming than comparable coal plants.

"If there is substantial natural gas leakage, then building new natural gas plants would lead to more near term climate damage than using the old dirty coal plants," explained Caldeira. "But natural gas plants would help reduce other types of air pollution that damage our health, and would be somewhat better for climate in the long term."

If faced with the choice of shutting down either a typical coal plant or a typical gas plant and methane leakage from the natural gas plant is below about 2 percent of total fuel, there would be a short-term climate benefit to shutting down the coal plant instead of the natural gas plant, the team found. But if methane leakage would be greater than 2 percent, there would be less warming in the near term if the natural gas plant were shut down instead of the coal plant.

Regardless, the team emphasized that meeting upcoming greenhouse gas emission targets will require deeper emissions cuts than just building natural gas plants with low methane leakage. If natural gas is to be a part of a future near-zero emission energy economy, methods for capturing and storing carbon from gas-fired power plants will likely be necessary.

Source: Carnegie Institution

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In world first, researchers convert sunlight to electricity with over 40 percent efficiency

Solar panels

UNSW Australia's solar researchers have converted over 40% of the sunlight hitting a solar system into electricity, the highest efficiency ever reported.

The record efficiency was achieved in outdoor tests in Sydney, before being independently confirmed by the National Renewable Energy Laboratory (NREL) at their outdoor test facility in the United States.

The work was funded by the Australian Renewable Energy Agency (ARENA) and supported by the Australia-US Institute for Advanced Photovoltaics (AUSIAPV).

"This is the highest efficiency ever reported for sunlight conversion into electricity," UNSW Scientia Professor and Director of the Advanced Centre for Advanced Photovoltaics (ACAP) Professor Martin Green said.

"We used commercial solar cells, but in a new way, so these efficiency improvements are readily accessible to the solar industry," added Dr Mark Keevers, the UNSW solar scientist who managed the project.

The 40% efficiency milestone is the latest in a long line of achievements by UNSW solar researchers spanning four decades. These include the first photovoltaic system to convert sunlight to electricity with over 20% efficiency in 1989, with the new result doubling this performance.

"The new results are based on the use of focused sunlight, and are particularly relevant to photovoltaic power towers being developed in Australia," Professor Green said.

Power towers are being developed by Australian company, RayGen Resources, which provided design and technical support for the high efficiency prototype. Another partner in the research was Spectrolab, a US-based company that provided some of the cells used in the project.

A key part of the prototype's design is the use of a custom optical bandpass filter to capture sunlight that is normally wasted by commercial solar cells on towers and convert it to electricity at a higher efficiency than the solar cells themselves ever could.

Such filters reflect particular wavelengths of light while transmitting others.

ARENA CEO Ivor Frischknecht said the achievement is another world first for Australian research and development and further demonstrates the value of investing in Australia's renewable energy ingenuity.

"We hope to see this home grown innovation take the next steps from prototyping to pilot scale demonstrations. Ultimately, more efficient commercial solar plants will make renewable energy cheaper, increasing its competitiveness."

The 40% efficiency achievement is outlined in a paper expected to be published soon by the Progress in Photovoltaics journal. It will also be presented at the Australian PV Institute's Asia-Pacific Solar Research Conference, which begins at UNSW Monday, December 8.

Source: University of New South Wales.

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The Matched 'hybrid' systems may hold key to wider use of renewable energy

Wind farms such as this one in Idaho might be combined with other forms of alternative energy to better balance the output of sustainable energy. Credit: Nordex USA/US Department of Energy

The use of renewable energy in the United States could take a significant leap forward with improved storage technologies or more efforts to "match" different forms of alternative energy systems that provide an overall more steady flow of electricity, researchers say in a new report.

Historically, a major drawback to the use and cost-effectiveness of alternative energy systems has been that they are too variable -- if the wind doesn't blow or the sun doesn't shine, a completely different energy system has to be available to pick up the slack. This lack of dependability is costly and inefficient.

But in an analysis just published in The Electricity Journal, scientists say that much of this problem could be addressed with enhanced energy storage technology or by developing "hybrid" systems in which, on a broader geographic scale, one form of renewable energy is ramping up even while the other is declining.

"Wind energy is already pretty cost-competitive and solar energy is quickly getting there," said Anna Kelly, a graduate student in the School of Public Policy at Oregon State University, and an energy policy analyst. "The key to greater use of these and other technologies is to match them in smart-grid, connected systems.

"This is already being done successfully in a number of countries and the approach could be expanded."

For instance, the wind often blows more strongly at night in some regions, Kelly said, and solar technology can only produce energy during the day. By making more sophisticated use of that basic concept in a connected grid, and pairing it with more advanced forms of energy storage, the door could be opened for a much wider use of renewable energy systems, scientists say.

"This is more than just an idea, it's a working reality in energy facilities around the world, in places like Spain, Morocco and China, as well as the U.S.," Kelly said. "Geothermal is being paired with solar; wind and solar with lithium-ion batteries; and wind and biodiesel with batteries. By helping to address the price issue, renewable energy is being produced in hybrid systems by real, private companies that are making real money."

Advanced energy storage could be another huge key to making renewable energy more functional, and one example is just being developed in several cooperating states in the West. Electricity is being produced by efficient wind farms in Wyoming; transmitted to Utah where it's being stored via compressed air in certain rock formations; and ultimately used to help power Los Angeles.

This $8 billion system could be an indicator of things to come, since compressed air can rapidly respond to energy needs and be readily scaled up to be cost-competitive at a significant commercial level.

"There are still a number of obstacles to overcome," said Joshua Merritt, a co-author on the report and also a graduate student in mechanical engineering and public policy at OSU. "Our transmission grids need major improvements so we can more easily produce energy and then send it to where it's needed. There are some regulatory hurdles to overcome. And the public has to more readily accept energy systems like wind, wave or solar in practice, not just in theory."

The "not in my back yard" opposition to renewable energy systems is still a reality, the researchers said, and there are still some environmental concerns about virtually any form of energy, whether it's birds killed by wind turbine rotors, fish losses in hydroelectric dams or chemical contaminants from use of solar energy.

The near future may offer more options, the researchers said. Advanced battery storage technologies are becoming more feasible. Wave or tidal energy may become a real contributor, and some of those forces are more predictable and stable by definition. And the birth of small, modular nuclear reactors -- which can be built at lower cost and produce no greenhouse gas emissions -- could play a significant role in helping to balance energy outflows from renewable sources.

The long-term goal, the report concluded, is to identify technologies that can work in a hybrid system that offers consistency, dependability and doesn't rely on fossil fuels. With careful matching of systems, improved transmission abilities and some new technological advances, that goal may be closer than realized, they said.

"With development, the cost of these hybrid systems will decrease and become increasingly competitive, hopefully playing a larger role in power generation in the future," the researchers wrote in their conclusion.

Source: Oregon State University

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New laws threaten Brazil's unique ecosystems

Brazil's globally significant ecosystems could be exposed to mining and dams if proposals currently being debated by the Brazilian Congress go ahead, according to researchers publishing in the journal Science this week. Credit: Alexander C. Lees

Brazil´s globally significant ecosystems could be exposed to mining and dams if proposals currently being debated by the Brazilian Congress go ahead, according to researchers publishing in the journal Science this week.

The new report by a group of Brazilian and British researchers comes in the wake of Brazil´s recent presidential elections. It warns that new legislation could pose a serious threat to protected areas, weakening Brazil's international status as an environmental leader.

One of the proposals of particular concern is the call to open up 10% of the most strictly protected areas to mining. In a new analysis, the research shows that at least 20% of all Brazil´s most strictly protected areas and reserves for indigenous people overlap with areas that have been registered as under consideration for mining. In addition, many of the river systems associated with protected areas will be influenced by the construction of large hydroelectric dams.

The threat that this mining and hydropower poses to Brazil's ecosystems is not trivial. Areas of registered interest for mining include 34,117 km2 that are currently classified as strictly protected areas -- including National Parks, Biological Reserves and Wildlife Refuges. This is equivalent to an area the size of Switzerland. The situation is worse for indigenous lands, 28% of which, or 281,443 km2, overlap with areas of registered mining interest -- an area larger than the whole of the UK or the state of São Paulo.

In recent years Brazil has enjoyed increasing recognition as a world leader in combatting environmental destruction. Brazil´s protected area network is the largest in the world, while improved environmental governance in private lands has contributed to an 80% reduction in the rate of deforestation in the Brazilian Amazon over the last decade. Yet these new proposals could threaten these recent successes and undermine Brazil's reputation.

Dr Joice Ferreira, a scientist at Brazil´s agricultural research institute, Embrapa, and lead author of the study, said: "The purpose of this analysis is not to say that Brazil´s development should not benefit from its abundant natural resources, but that we should not squander our hard-won record of success and leadership in favor of fast-tracked and poorly planned development projects that leave a long legacy of environmental damage. It is possible to manage our development in a more sustainable way."

Co-author Dr Jos Barlow, a researcher at Lancaster University and a visiting professor in Brazil, said: "Rather than exploiting protected areas for short-term gains, Brazil should treasure them for the long-term benefits they can provide to society. The recent water shortages in the south east of Brazil emphasize the importance of protecting native vegetation across the country."

The authors of the study also warn that the proposals for minimizing and mitigating the environmental damage of large-scale development projects are so inadequate that even if only a fraction of these mining concessions were approved then the impacts could be enormous, especially in Brazil´s most threatened ecosystems.

Dr. Luiz Aragão a co-author of the study from Brazil´s federal space agency, INPE and the University of Exeter said: "Our concern is that even if the proposed mitigation actions were put in place they are oversimplified because they fail to take account of the indirect effects of mega-projects.
"These projects can involve thousands of workers and lead to rapid local population growth. This, combined with new roads and access routes, is a recipe for the emergence of new deforestation frontiers." explains Luiz.

The study highlights the fact that these worrying changes reflect an important shift in the support shown by Brazil´s federal government to environmental protection. These concerns come on the back of other recent changes, including the partial dismantling of Brazil´s protected area system to make way for development -- with some 44,100 km2 lost since 2008 due to downsizing or abolishment -- and the weakening of the Forest Code that gave an amnesty to landowners who deforested illegally in the past.

"Beyond the conservation and stewardship of its own biodiversity and environmental resources, so vital to the wellbeing of its citizens, Brazil plays a vital role in motivating and supporting the adoption of more sustainable development trajectories around the world," said Toby Gardner, of Stockholm Environment Institute, one of the authors of the study who has worked in the country for more than a decade. "Yet this standing is now in jeopardy."

Dr Joice Ferreira said: "The newly elected government has the chance to set the record straight and point Brazil firmly on a path of sustainable development. The authors of this report call on President Dilma and her government to ensure that individual development initiatives are subject to a comprehensive, socially inclusive, evidence-based and long-term cost-benefit analysis that compares potential environmental and social impacts against alternative development options. And also to ensure that Brazil´s renowned protected area network is given the resources it needs to manage our ecosystems sustainably.

"Above all we ask the Government to guarantee that important decisions regarding the management of Brazil´s natural resources involve the full and democratic participation of Brazilian society."

Source: Lancaster University

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Heavy metals and hydroelectricity

August 2014 GSA Today cover image: The northeastern shoreline of Lake Junín, Peru. The pristine water surface belies a high level of heavy metal contamination of surface sediments. Credit: Donald T. Rodbell

Hydraulic engineering is increasingly relied on for hydroelectricity generation. However, redirecting stream flow can yield unintended consequences. In the August 2014 issue of GSA Today, Donald Rodbell of Union College-Schenectady and coauthors from the U.S. and Peru document the wholesale contamination of the Lake Junín National Reserve by acid mine drainage from the Cerro de Pasco mining district.

According to the World Bank, about 60% of Peru's electricity is generated by hydropower, which during the dry season relies heavily on glacial meltwater to augment stream flow. The ongoing reduction in ice cover in Peru that began early in the twentieth century has reduced the aerial extent of glacial ice in some areas by nearly 30%. According to this GSA Today article, climate models project that warming will be pronounced in the highest elevation regions of the tropical Andes, and thus acceleration in ice loss is likely.

To maintain dry-season river discharge and energy generation for a growing Peruvian population, the hydropower industry in Peru has turned to hydraulic engineering, including dam construction. This study highlights an unintended consequence of early dam construction in the Cerro de Pasco region of the central Peruvian Andes, a region that has been a focal point of Peruvian mining operations for centuries.

The Cerro de Pasco mining district is among the most extensively worked mining districts in Peru. Pre-colonial mining there showed some of the earliest evidence of anthropogenic lead enrichment by aerosolic fallout in nearby lakes about 600 years ago. The first copper smelter was established there in 1906, and in 1931 the new and improved Cerro smelter held monopoly over the refining of all nonferrous metals in Peru.

In order to generate hydroelectricity for Cerro de Pasco's operations, the Upamayo Dam was constructed in 1932. The Upamayo Dam is located in the uppermost reach of the Río Mantaro, immediately downstream of the confluence between the Río San Juan, which drains southward from Cerro de Pasco, and the outflow of Lake Junín, the largest lake entirely within Peru.

The location of the Upamayo Dam and the small reservoir upstream from it has resulted in the discharge of Río San Juan waters, once destined for the Río Mantaro, directly into Lake Junín. Rodbell et al.'s GSA Today paper documents the impact of acid mine drainage from Cerro de Pasco into Lake Junín, which in 1974 was designated a Peruvian National Wildlife Reserve.

As a result of the drainage, the upper several decimeters of sediment in the lake now contain levels of lead and zinc that greatly exceed the U.S. Environmental Protection Agency limits for the lake basin. Today, more than 60,000 metric tons of copper, almost 900,000 metric tons of zinc, and almost 41,000 metric tons of lead are contained in the upper 50 cm of lake sediment -- the zinc tonnage representing more than five years' worth of mining production at current rates.

Rodbell and colleagues write that among the biggest challenges that will face any attempt to mitigate the environmental disaster that has befallen Lake Junín are finding ways to stop the recycling of zinc from the lake bottom and the remobilization of all metals from the seasonally exposed and submerged deposits that are trapped behind the Upamayo Dam. Finally, they note that as future hydraulic engineering projects are developed in Peru and elsewhere, it would behoove all not to repeat the mistakes that are recorded in the mud of Lake Junín.

Source: Geological Society of America

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New technology successfully removes heavy metals from water

Polluted water.
Credit: Image courtesy of Investigación y Desarrollo

The methods traditionally used to remove heavy metals from wastewater have limitations because they only withdraw a certain percentage and the remaining amount is very difficult to remove. This motivated a young graduate researcher at the National Polytechnic Institute (IPN) in Mexico, Gabriel Ramirez Monter, to create a technology capable of removing such contaminants at low cost and with an efficiency that surpasses existing technologies.

According to Monter Ramirez, this project led him to design some structures called dendrimers, which are highly branched molecules with shape similar to a shrub or a tree with multiple branches.
"Dendrimers adhere and spread on a microfiltration membrane; ie, thin sheets of porous material that are not normally capable of retaining heavy metals due to its pore size. Once placed, it achieves total removal of heavy metal ions in the same way a marine anemone would act, using tentacles to concentrate and catch food; in this case, the branches of the dendrimers capture pollutants, "says the researcher.

He explains that through dendrimers the team converted a microfiltration membrane into a nanofiltration one. "Another advantage of these structures is that they can be washed and reused, plus the captured metals are removed without problem."

Highlighting his business plan, which he called "Nanoestructurados Bromelia", it integrates his master's work, led by Dr. Irina Victorovna Lijanova attached to the Centre for Research and Technological Innovation (CIITEC) of the IPN, which has optimized technologies for removal of heavy metals.

Currently, the entrepreneurial project is linked to the company "Nanotecnología México" that specializes in nanomaterials with applications for the environment and is a leading provider of Mexican Oil (Pemex) in the refining area for sewage cleanup. "The firm was interested in the development of this technology and its commercialization," said Monter Ramirez.

"In Mexico, the problem of heavy metals is associated with industrial progress and important economic activities such as mining or even the oil industry, in both refining and petrochemicals; those are the markets we want to focus on," he stresses.

Source: Investigación y Desarrollo.

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Recovering metals and minerals from waste

When water and wastewater systems are developed in a comprehensive manner, it is possible to recover valuable metals and other materials and secure availability of clean water.

Scarcity of clean water is one of the most serious global challenges. In its spearhead programme, VTT Technical Research Centre of Finland developed energy-efficient methods for reuse of water in industrial processes and means for recovering valuable minerals and materials from waste for recycling. Rapid tools were also developed for identification of environmental pollutants.

When water and wastewater systems are developed in a comprehensive manner, it is possible to recover valuable metals and other materials and secure availability of clean water. Cleaning and treatment processes can also be linked to energy production, and the processes and urban structures designed in such a manner that wastewater treatment does not consume energy or cause extra costs.

"Wastewater treatment and waste treatment have mainly been implemented by legal necessity. Now we should modify our way of thinking so that we would be able to regard waste disposal sites and purification plants as sources or raw materials and energy. In the near future, technology has been refined far enough to allow such waste treatment plants to operate on their own," says Mona Arnold, Principal Researcher at VTT.

Recycling valuable minerals and materials

Demand has arisen for technologies capable of recovering even tiny amounts of minerals from waste flows. Recovering them from municipal or mining wastewaters requires better recovery methods than those available today. VTT has developed extraction methods for metals and minerals from waste materials. Biological extraction methods by which metals are recovered from mining, metal and recycling industry waste by utilising microbes and chemical reactions are under testing stages and they are forcasted for market uptake within the next few years.

Other valuable elements can also be found from waste flows. For example, the food industry by-product flows contain biochemicals and proteins that can be utilised better than is currently possible, if only they could be effectively recovered from waste. One possibility is to use enzymes. VTT researchers developed an enzyme-assisted method by which feed products can be produced from side streams deriving from turnip rape processing in food industry.

Reducing energy consumption in water treatment

Treatment of water in purification plants and industrial facilities consumes vast amounts of energy. Usually water recycling and seawater desalination are based on the use of filtration membranes that consume energy. VTT developed intelligent membrane materials, reducing the need of purification, for filtration purposes.

Membrane solutions using only small amounts of energy were developed for water treatment purposes. VTT has collaborated with a university in Singapore to develop a method based on forward osmosis technology, by which metals and biocomponents can be recovered and concentrated from industrial process waters.

The pumping and distribution of water to consumers and industry also consumes major amounts of energy. The need for pumping can be minimised if the process water can be recirculated within the plant, and the distribution network is made more effective by enhanced monitoring and location of leaks.

Sensors for identifying environmental hazards

The VTT spearhead programme also developed sensor technology for easy and rapid detection of pollutants. VTT indicators facilitate rapid identification of, for example, small but hazardous cyanobacterial toxin levels and phenolic, hormone-like compounds. There is need for such indicators in developing countries, suffering from lack of trained personnel and laboratories. The technology will be ready for production use within the next few years.

Source: Technical Research Centre of Finland (VTT).

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Maize and bacteria: A one-two punch knocks copper out of stamp sand

Maize plants grown in stamp sand inoculated with bacteria, left, were considerably more robust than those grown in stamp sand alone, right. This research could lead to new remediation techniques for soils contaminated by copper and other heavy metals.
Credit: Image courtesy of Michigan Technological University

Scientists have known for years that together, bacteria and plants can remediate contaminated sites. Ramakrishna Wusirika, of Michigan Technological University, has determined that how you add bacteria to the mix can make a big difference.

He has also shed light on the biochemical pathways that allow plants and bacteria to clean up some of the worst soils on the planet while increasing their fertility.

Wusirika, an associate professor of biological sciences, first collected stamp sands near the village of Gay, in Michigan's Upper Peninsula. For decades, copper mining companies crushed copper ore and dumped the remnants -- an estimated 500 million tons of stamp sand -- throughout the region. Almost nothing grows on these humanmade deserts, which are laced with high concentrations of copper, arsenic and other plant-unfriendly chemicals.

Then, Wusirika and his team planted maize in the stamp sand, incorporating bacteria in four different ways:
1. mixing it in the stamp sand before planting seed;
2. coating seed with bacteria and planting it;
3. germinating seeds and planting them in soil to which bacteria were added; and
4. the conventional method, immersing the roots of maize seedlings in bacteria and planting them in stamp sand.

After 45 days, the team uprooted the plants and measured their dry weight. All maize grown with bacteria was significantly more vigorous -- from two to five times larger -- than the maize grown in stamp sand alone. The biggest were those planted as seedlings or as germinated seeds.

However, when the researchers analyzed the dried maize, they made a surprising discovery: the seed-planted maize took up far more copper as a percentage of dry weight. In other words, the smaller plants pulled more copper, ounce per ounce, out of the stamp sands than the bigger ones.

That has implications for land managers trying to remediate contaminated sites, or even for farmers working with marginal soils, Wusirika said. The usual technique -- applying bacteria to seedlings' roots before transplanting -- works fine in the lab but would be impractical for large-scale projects. This could open the door to simple, practical remediation of copper-contaminated soils.

But the mere fact that all the plants grown with bacteria did so well also piqued his curiosity. "When we saw this, we wondered what the bacteria were doing to the soil," Wusirika said. "Based on our research, it looks like they are improving enzyme activity and increasing soil fertility," in part by freeing up phosphorus that had been locked in the rock.

The bacteria are also changing copper into a form that the plants can take up. "With bacteria, the exchangeable copper is increased three times," he said. "There's still a lot of copper that's not available, but it is moving in the right direction."

By analyzing metabolic compounds, the team was able to show that the bacteria enhance photosynthesis and help the plants make growth hormones. Bacteria also appear to affect the amount phenolics produced by the maize. Phenolics are antioxidants similar to those in grapes and red wine.
Compared to plants grown in normal soil without bacteria, plants grown in stamp sand alone showed a five-fold increase in phenolics. However, phenolics in plants grown in stamp sand with bacteria showed a lesser increase.

"Growing in stamp sand is very stressful for plants, and they respond by increasing their antioxidant production," Wusirika said. "Adding the metal-resistant bacteria enables the plants to cope with stress better, resulting in reduced levels of phenolics."

"There's still a lot to understand here," he added. "We'd like to do a study on stamp sands in the field, and we'd also like to work with plants besides maize. We think this work has applications in organic agriculture as well as remediation."

Source:  Michigan Technological University

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Environmental costs, health risks, and benefits of fracking examined

This is a fracking operations at a well pad near a farm over the Marcellus shale formation in Pennsylvania.
Credit: Robert Jackson, Stanford University

A strange thing happened on the way to dealing with climate change: Advances in hydraulic fracturing put trillions of dollars' worth of previously unreachable oil and natural gas within humanity's grasp.

The environmental costs -- and benefits -- from "fracking," which requires blasting huge amounts of water, sand and chemicals deep into underground rock formations, are the subject of new research that synthesizes 165 academic studies and government databases. The survey covers not only greenhouse gas impacts but also fracking's influence on local air pollution, earthquakes and, especially, supplies of clean water.

The authors are seven environmental scientists who underscore the real consequences of policy decisions on people who live near the wells, as well as some important remaining questions.
"Society is certain to extract more gas and oil due to fracking," said Stanford environmental scientist Robert Jackson, who led the new study. "The key is to reduce the environmental costs as much as possible, while making the most of the environmental benefits."

Fracking's consumption of water is rising quickly at a time when much of the United States is suffering from drought, but extracting natural gas with hydraulic fracturing and horizontal drilling compares well with conventional energy sources, the study finds. Fracking requires more water than conventional gas drilling; but when natural gas is used in place of coal or nuclear fuel to generate electricity, it saves water. From mining to generation, coal power consumes more than twice the water per megawatt-hour generated than unconventional gas does.

Unconventional drilling's water demand can be better or worse than alternative energy sources, the study finds. Photovoltaic solar and wind power use almost no water and emit no greenhouse gas, but cheap, abundant natural gas may limit their deployment as new sources of electricity. On the other hand, fracked gas requires less than a hundredth the water of corn ethanol per unit of energy.

Fracking's impact on both climate change and local air pollution is similar to its impact on water, finds the study "The Environmental Costs and Benefits of Fracking," published in the Annual Review of Environment and Resources.

Getting a fractured well going is more intense than for conventional oil and gas drilling, with potential health threats arising from increases in volatile organic compounds and air toxics.

But when natural gas replaces coal as a fuel for generating electricity, the benefits to air quality include lower carbon dioxide emissions than coal and almost none of the mercury, sulfur dioxide or ash.

Globally, though, relief to climate change is uncertain, the study finds. "While the increased gas supply reduces air pollution in U.S. cities downwind from coal-fired power plants, we still don't know whether methane losses from well pads and pipelines outweigh the lower carbon dioxide emissions," said Jackson.

In the eastern United States, fears of contaminated drinking water have raised more concerns than fracking's water consumption. Gas and chemicals from humanmade fractures thousands of meters underground very rarely seep upward to drinking-water aquifers, the study says. The real threats are failures in the steel and cement casings of wells nearer to the surface and the disposal of wastewater, the study finds. Numerous previous studies have shown that casings fail between 1 percent and 10 percent of the time, depending on geology and well construction.

Cases of groundwater contamination have been hotly debated, but the new study finds that the overwhelming evidence suggests it has happened, albeit not commonly. Is the methane contamination observed in drinking water a precursor to other toxins -- arsenic, various salts, radioactive radium and other metals -- making their way up slowly? The researchers do not yet know. A few recent studies suggest the answer could be "yes" in rare cases.

How oil and gas companies handle wastewater -- fluid used to fracture the shale that flows back up the well and water unleashed with the oil and gas -- shows the importance of state policies. "Wastewater disposal is one of the biggest issues associated with fracking," said co-author Avner Vengosh, a professor of geochemistry at Duke University.

Most fracking wastewater in the United States is injected deep underground, and an increasing amount is recycled for subsequent drilling or sent to advanced water treatment facilities. However, a handful of states still allow the wastewater to be used for watering cattle, sprayed onto roads for dust control or sent to municipal water-treatment plants not equipped to handle the chemicals involved.

All bad ideas, according to the authors of the new survey, who work at Duke University, MIT, Ohio State University, Newcastle University, Los Alamos National Laboratory, the National Oceanic and Atmospheric Administration and Stanford. One study they cite found that the agricultural use of fracking wastewater killed more than half of nearby trees within two years.

Injection of wastewater deep underground presents its own problems, the study finds. The practice occasionally has caused earthquakes strong enough to be felt by human beings, while the fracturing of shale miles below the surface rarely has done so. The dangers of seismicity can be reduced, however, if energy companies follow basic guidelines and undertake careful monitoring.

The study highlights several policies and practices that could optimize fracking's environmental cost-benefit balance, and it highlights the need for further research. For example, the direct impact on the health of nearby residents is virtually unknown. "Almost no comprehensive research has been done on health effects," said Jackson, "but decisions about drilling -- both approvals and bans on fracking -are made all the time based on assumptions about health risks."

Source: Stanford University

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