A new step towards using graphene in electronic applications

(A) This image is a diagram of molecular precursors, the resulting graphene nanoribbons and the heterostructured ones. (B) Tunnel microscopy images of the heterostructures synthesized on gold surfaces. Credit: UPV/EHU

Few materials have received as much attention from the scientific world or have raised so many hopes with a view to their potential deployment in new applications as graphene has. This is largely due to its superlative properties: it is the thinnest material in existence, almost transparent, the strongest, the stiffest and at the same time the most strechable, the best thermal conductor, the one with the highest intrinsic charge carrier mobility, plus many more fascinating features. Specifically, its electronic properties can vary enormously through its confinement inside nanostructured systems, for example. That is why ribbons or rows of graphene with nanometric widths are emerging as tremendously interesting electronic components. On the other hand, due to the great variability of electronic properties upon minimal changes in the structure of these nanoribbons, exact control on an atomic level is an indispensable requirement to make the most of all their potential.

The lithographic techniques used in conventional nanotechnology do not yet have such resolution and precision. In the year 2010, however, a way was found to synthesise nanoribbons with atomic precision by means of the so-called molecular self-assembly. 

Molecules designed for this purpose are deposited onto a surface in such a way that they react with each other and give rise to perfectly specified graphene nanoribbons by means of a highly reproducible process and without any other external mediation than heating to the required temperature. In 2013 a team of scientists from the University of Berkeley and the Centre for Materials Physics (CFM), a mixed CSIC (Spanish National Research Council) and UPV/EHU (University of the Basque Country) centre, extended this very concept to new molecules that were forming wider graphene nanoribbons and therefore with new electronic properties. This same group has now managed to go a step further by creating, through this self-assembly, heterostructures that blend segments of graphene nanoribbons of two different widths.

The forming of heterostructures with different materials has been a concept widely used in electronic engineering and has enabled huge advances to be made in conventional electronics. "We have now managed for the first time to form heterostructures of graphene nanoribbons modulating their width on a molecular level with atomic precision. What is more, their subsequent characterisation by means of scanning tunnelling microscopy and spectroscopy, complemented with first principles theoretical calculations, has shown that it gives rise to a system with very interesting electronic properties which include, for example, the creation of what are known as quantum wells," pointed out the scientist Dimas de Oteyza, who has participated in this project. This work, the results of which are being published this very week in the journal Nature Nanotechnology, therefore constitutes a significant success towards the desired deployment of graphene in commercial electronic applications.

Dr Dimas G. de Oteyza, who was previously at Berkeley and at the CFM, is currently working at the Donostia International Physics Center (DIPC) as a Fellow Gipuzkoa.

Source: University of the Basque Country

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Switching to vehicles powered by electricity from renewables could save lives

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. Credit: © Dmitry Vereshchagin / Fotolia

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. This finding comes from a new life cycle analysis of conventional and alternative vehicles and their air pollution-related public health impacts, published Monday, Dec. 15, 2014, in the Proceedings of the National Academy of Sciences.

The study also shows that switching to vehicles powered by electricity made using natural gas yields large health benefits. Conversely, vehicles running on corn ethanol or vehicles powered by coal-based or "grid average" electricity are worse for health; switching from gasoline to those fuels would increase the number of resulting deaths due to air pollution by 80 percent or more.

"These findings demonstrate the importance of clean electricity, such as from natural gas or renewables, in substantially reducing the negative health impacts of transportation," said Chris Tessum, co-author on the study and a researcher in the Department of Civil, Environmental, and Geo- Engineering in the University of Minnesota's College of Science and Engineering.

The University of Minnesota team estimated how concentrations of two important pollutants -- particulate matter and ground-level ozone -- change as a result of using various options for powering vehicles. Air pollution is the largest environmental health hazard in the U.S., in total killing more than 100,000 people per year. Air pollution increases rates of heart attack, stroke, and respiratory disease.

The authors looked at liquid biofuels, diesel, compressed natural gas, and electricity from a range of conventional and renewable sources. Their analysis included not only the pollution from vehicles, but also emissions generated during production of the fuels or electricity that power them. With ethanol, for example, air pollution is released from tractors on farms, from soils after fertilizers are applied, and to supply the energy for fermenting and distilling corn into ethanol.

"Our work highlights the importance of looking at the full life cycle of energy production and use, not just at what comes out of tailpipes," said Bioproducts and Biosystems Engineering Assistant Professor Jason Hill, co-author of the study. "We greatly underestimate transportation's impacts on air quality if we ignore the upstream emissions from producing fuels or electricity."

The researchers also point out that whereas recent studies on life cycle environmental impacts of transportation have focused mainly on greenhouse gas emissions, it is also important to consider air pollution and health. Their study provides a unique look at where life cycle emissions occur, how they move in the environment, and where people breathe that pollution. Their results provide unprecedented detail on the air quality-related health impacts of transportation fuel production and use.

"Air pollution has enormous health impacts, including increasing death rates across the U.S.," said Civil, Environmental and Geo- Engineering Associate Professor Julian Marshall, co-author on this study. "This study provides valuable new information on how some transportation options would improve or worsen those health impacts."

Source: University of Minnesota

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What's in the grime tarnishing the Taj Mahal?

Taj Mahal

Every several years, workers apply a clay mask to India's iconic but yellowing Taj Mahal to remove layers of grime and reveal the white marble underneath. Now scientists are getting to the bottom of what kinds of pollutants are discoloring one of the world's celebrated wonders. Their findings, published in the ACS journal Environmental Science & Technology, could help inform efforts to protect the mausoleum and other surfaces from pollution.

Mike H. Bergin, Sachchida Nand Tripathi and colleagues note that Indian officials have tried to reduce the effects of pollution on the Taj Mahal by restricting nearby traffic and limiting local industrial emissions. But despite regulations and an occasional deep clean, the domes and minarets continue to accrue a layer of soot. So far, no published studies have looked closely at what specific compounds are causing it to appear yellow. Bergin's and Tripathi's teams wanted to find out.

The researchers analyzed particles in the air and on marble samples near the main dome over several months. Using a novel method they developed, the team estimated how these specks reflect light and therefore affect the color of the building. They conclude that black carbon and brown carbon from the burning of trash, fuels and other materials are among the primary pollutants tarnishing the Taj Mahal. In the future, their approach could be used to craft strategies to address the chronic yellowing and improve air quality, they say.

The authors acknowledge funding from the Indo-U.S. Science and Technology Forum, the Environmental Protection Agency and the National Science Foundation.

Source: American Chemical Society

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Soil mineral surfaces linked to key atmospheric processes

Pictured are, from left, are David Bish, Melissa Donaldson and Jonathan Raff. Credit: Indiana University

Research by Indiana University scientists finds that soil may be a significant and underappreciated source of nitrous acid, a chemical that plays a pivotal role in atmospheric processes such as the formation of smog and determining the lifetime of greenhouse gases.

The study shows for the first time that the surface acidity of common minerals found in soil determines whether the gas nitrous acid will be released into the atmosphere. The finding could contribute to improved models for understanding and controlling air pollution, a significant public health concern.

"We find that the surfaces of minerals in the soil can be much more acidic than the overall pH of the soil would suggest," said Jonathan Raff, assistant professor in the School of Public and Environmental Affairs and Department of Chemistry. "It's the acidity of the soil minerals that acts as a knob or a control lever, and that determines whether nitrous acid outgasses from soil or remains as nitrite."

The article, "Soil surface acidity plays a determining role in the atmospheric-terrestrial exchange of nitrous acid," will be published this week in the journal Proceedings of the National Academy of Sciences. Melissa A. Donaldson, a Ph.D. student in the School of Public and Environmental Affairs, is the lead author. Co-authors are Raff and David L. Bish, the Haydn Murray Chair of Applied Clay Mineralogy in the Department of Geological Sciences.

Nitrous acid, or HONO, plays a key role in regulating atmospheric processes. Sunlight causes it to break down into nitric oxide and the hydroxyl radical, OH. The latter controls the atmospheric lifetime of gases important to air quality and climate change and initiates the chemistry leading to the formation of ground-level ozone, a primary component of smog.
Scientists have known about the nitrous acid's role in air pollution for 40 years, but they haven't fully understood how it is produced and destroyed or how it interacts with other substances, because HONO is unstable and difficult to measure.

"Only in the last 10 years have we had the technology to study nitrous acid under environmentally relevant conditions," Raff said.

Recent studies have shown nitrous acid to be emitted from soil in many locations. But this was unexpected because, according to basic chemistry, the reactions that release nitrous acid should take place only in extremely acidic soils, typically found in rain forests or the taiga of North America and Eurasia.

The standard method to determine the acidity of soil is to mix bulk soil with water and measure the overall pH. But the IU researchers show that the crucial factor is not overall pH but the acidity at the surface of soil minerals, especially iron oxides and aluminum oxides. At the molecular level, the water adsorbed directly to these minerals is unusually acidic and facilitates the conversion of nitrite in the soil to nitrous acid, which then volatilizes.

"With the traditional approach of calculating soil pH, we were severely underestimating nitrous acid emissions from soil," Raff said. "I think the source is going to turn out to be more important than was previously imagined."

The research was carried out using soil from a farm field near Columbus, Ind. But aluminum and iron oxides are ubiquitous in soil, and the researchers say the results suggest that about 70 percent of Earth's soils could be sources of nitrous acid.

Ultimately, the research will contribute to a better understanding of how nitrous acid is produced and how it affects atmospheric processes. That in turn will improve the computer models used by the U.S. Environmental Protection Agency and other regulatory agencies to control air pollution, which the World Health Organization estimates contributes to 7 million premature deaths annually.

"With improved models, policymakers can make better judgments about the costs and benefits of regulations," Raff said. "If we don't get the chemistry right, we're not going to get the right answers to our policy questions regarding air pollution."

Source: Indiana University

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Microbiologists discover how gut bacterial resources are hijacked to promote intestinal, foodborne illnesses

Dr. Vanessa Sperandio. Credit: Image courtesy of UT Southwestern Medical Center

UT Southwestern Medical Center microbiologists have identified key bacteria in the gut whose resources are hijacked to spread harmful foodborne E. coli infections and other intestinal illnesses.

Though many E. coli bacteria are harmless and critical to gut health, some E. coli species are harmful and can be spread through contaminated food and water, causing diarrhea and other intestinal illnesses. Among them is enterohemorrhagic E. coli or EHEC, one of the most common foodborne pathogens linked with outbreaks featured in the news, including the multistate outbreaks tied to raw sprouts and ground beef in 2014.

The UT Southwestern team discovered that EHEC uses a common gut bacterium called Bacteroides thetaiotaomicron to worsen EHEC infection. B. thetaiotaomicron is a predominant species in the gut's microbiota, which consists of tens of trillions of microorganisms used to digest food, produce vitamins, and provide a barrier against harmful microorganisms.

"EHEC has learned to how to steal scarce resources that are made by other species in the microbiota for its own survival in the gut," said lead author Dr. Meredith Curtis, Postdoctoral Researcher at UT Southwestern.

The research team found that B. thetaiotaomicron causes changes in the environment that promote EHEC infection, in part by enhancing EHEC colonization, according to the paper, appearing in the journal Cell Host Microbe.

"We usually think of our microbiota as a resistance barrier for pathogen colonization, but some crafty pathogens have learned how to capitalize on this role," said Dr. Vanessa Sperandio, Professor of Microbiology and Biochemistry at UT Southwestern and senior author.

EHEC senses changes in sugar concentrations brought about by B. thetaiotaomicron and uses this information to turn on virulence genes that help the infection colonize the gut, thwart recognition and killing by the host immune system, and obtain enough nutrients to survive. The group observed a similar pattern when mice were infected with their equivalent of EHEC, the gut bacterium Citrobacter rodentium. Mice whose gut microbiota consisted solely of B. thetaiotaomicron were more susceptible to infection than those that had no gut microbiota. Once again, the research group saw that B. thetaiotaomicron caused changes in the environment that promoted C. rodentium infection.

"This study opens up the door to understand how different microbiota composition among hosts may impact the course and outcome of an infection," said Dr. Sperandio, whose lab studies how bacteria recognize the host and how this recognition might be exploited to interfere with bacterial infections. "We are testing the idea that differential gastrointestinal microbiota compositions play an important role in determining why, in an EHEC outbreak, some people only have mild diarrhea, others have bloody diarrhea and some progress to hemolytic uremic syndrome, even though all are infected with the same strain of the pathogen."

The Centers for Diseases Control and Prevention (CDC) estimates that each year roughly 1 in 6 Americans (or 48 million people) gets food poisoning; 128,000 are hospitalized;, and 3,000 die of their food-borne disease. EHEC, which also caused a widespread outbreak in Europe in 2011, can lead to bloody diarrhea, hemorrhagic colitis, and hemolytic uremic syndrome, which in turn can lead to kidney disease and failure. EHEC is among the top five pathogens contributing to domestically acquired foodborne illnesses resulting in hospitalization, according to the CDC. Outbreaks in 2014 were reported in California, Idaho, Massachusetts, Michigan, Missouri, Ohio, Montana, Utah, and Washington.

Source: UT Southwestern Medical Center

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Microplastics in the ocean: Biologists study effects on marine animals

A marine isopod of the genus Idotea with food pellets.
Credit: Photo Alfred Wegener Institute / Julia Hämer

Ingestion of microplastic particles does not mechanically affect marine isopods. This was the result of a study by biologists at the North Sea Office of the Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research (AWI) that was published recently in the journal Environmental Science and Technology. The study marks the launch of a series of investigations aimed at forming a risk matrix on the sensitivity of different marine species to microplastic pollution.

Uptake of large plastic items by birds and fish may cause blockage of the gastrointestinal tract and severe starvation of the animals. "We were wondering whether small plastic particles have a comparable effect on smaller animals," says Dr. Lars Gutow from AWI's North Sea Office. "Only very limited research has been done on the effects of microplastics on living beings. Accordingly, there is great uncertainty about the implications for marine animals," the biologist explains the motivation for the study.

Lars Gutow and his colleagues selected the isopod Idotea emarginata as their model organism for an initial case study. In feeding experiments the researchers offered the isopods artificial algal food supplemented with plastic particles. The food contained three different kinds of microplastics in varying concentrations. They used industrially produced polystyrene particles with a diameter of ten micrometers as well as self-made fragments and fibres made of polyethylene and polyacryl, respectively.

The researchers studied the fate of the different materials under a light microscope, with the help of a fluorescence microscope, and with an electron microscope. They were able to trace the path of the microplastic particles through the isopods and determine the concentrations of the particles in different sections of the digestive system. The study showed that the concentration of microplastics in the faecal material of the isopods was as high as in the food. The scientists found small amounts of microplastics both in the stomach and in the gut of the animals. However, they did not detect any microparticles in the digestive glands. "The isopods ingested and excreted the artificial food with the microplastic particles without absorbing or accumulating the particles," Gutow summarises the results. Thus, plastic particles in the specific size range studied do not represent a direct mechanical risk for isopods and probably not for other crustaceans either. "In the case of Idotea emarginata, the microplastic particles did not enter the digestive gland, which is the principle organ in crustaceans where digestion and resorption of nutrients takes place," states the biologist from AWI's North Sea Office.

In a long-term experiment the scientists could also show that isopods did not display any long-term effects even after feeding on microplastic enriched food for six to seven weeks. 

Fitness parameters such as survival rate and growth did not differ between animals that were fed with and without microplastics, respectively. In an earlier study, however, AWI biologist Prof. Dr. Angela Köhler demonstrated that mussels show inflammatory reactions if they take up and absorb high concentrations of microplastic in an experiment. This clearly shows that different animal species react differently to microplastics. "In contrast to filter feeding mussels, isopods of the genus Idotea probably take up more frequently indigestible particles with their food in their natural habitat and may, thus, have adapted accordingly," elucidates Gutow.

But the biologists are not only interested in the feeding type: "We want to study systematically how the life style, habitat, physiology and anatomy of different marine organisms influence the uptake and utilisation of microplastic particles in order to come up with a risk matrix for diverse types of organisms," says Lars Gutow. "Therefore, it will be necessary to also study the possible chemical (toxic) and biochemical effects in addition to the physical effects that we looked at," he outlines future tasks.

Source: Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research

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Nitrogen fingerprint in biomolecules could be from early sun

Ultraviolet light splits more readily splits molecules of nitrogen gas if one or both are the heavier isotope, nitrogen-15. Free nitrogen atoms combine with hydrogen to form ammonia molecules enriched in nitrogen-15. Credit: Image courtesy of University of California - San Diego

Chemical fingerprints of the element nitrogen vary by extremes in materials from the molecules of life to the solar wind to interstellar dust. Ideas for how this great variety came about have included alien molecules shuttled in by icy comets from beyond our solar system and complex chemical scenarios.

New experiments using a powerful source of ultraviolet light have shown that no extra-solar explanation is needed and the chemistry is straight forward, scientists from the University of California, San Diego, Hebrew University and UCLA report in the early online edition of the Proceedings of the National Academy of Sciences the week of September 29.

Nitrogen occurs in two stable forms. Nitrogen-14, with an equal number of protons and neutrons in its nucleus, is most abundant. Nitrogen-15, with an extra neutron, is far more rare, but biological molecules like proteins have larger proportions; they're enriched in nitrogen-15 relative to the nitrogen gas in Earth's atmosphere. And Earth's atmosphere itself has relatively more nitrogen-15 than other sources, such as the solar wind and Jupiter's atmosphere.

Samples from the icy comet Wild 2, retrieved by NASA's Stardust mission, and several kinds of meteorites also have relatively more nitrogen-15, and within the inhomogenous mix that makes up stony meteorites are inclusions, individual crystals that can have extremely high proportions of nitrogen-15. These observations led to the idea that the building blocks of life could have been 'seeded' on Earth, delivered perhaps by comet.

The new experiments render that hypothesis unnecessary. "We can generate this nitrogen enrichment inside the solar system. You can form all these building blocks of life inside our solar system. You don't have to bring the pieces in from outside," said Subrata Chakraborty, a project scientist in chemistry at UC San Diego and lead author of the report.

By shining a bright beam of very short wave ultraviolet light through nitrogen and hydrogen gas, Chakraborty and colleagues generated ammonia with drastically skewed ratios of nitrogen-15 relative to that found in the initial gas, which matched that of Earth's atmosphere. Pairs of nitrogen atoms -- the molecules of the gas -- were more likely to be split by UV photons if one or both atoms are the heavier version. Those freed nitrogen atoms recombined with hydrogen to form ammonia.

Ammonia molecules, a nitrogen atom bound to three hydrogen atoms, makes up a fundamental chemical group, the 'amines' the characterize amino acids, which link up in long chains to form proteins. They also join aromatic rings of carbon to form nitrogenous bases, the information carrying components of DNA and RNA. And RNA is how many think life got its start.

Light like this, with wavelengths this short, doesn't make it to Earth anymore. It's deflected by Earth's atmosphere. In fact, the experiments took place in a custom-engineered vacuum chamber aligned with the Lawrence Berkeley National Laboratory's Advanced Light Source synchrotron and were a challenge to pull off.

The chemical events that produced amines with extra nitrogen-15 would have happened long ago, probably in the icy outer reaches of the early solar nebula said Mark Thiemens, professor of chemistry at UC San Diego who directed the work. "It's the right time for this to have happened: before planets, before life."

Additional authors include Harel Muskatel of Hebrew University in Jerusalem, Teresa Jackson of UC San Diego, Musahid Ahmed of Lawrence Berkeley National Laboratory and R.D. Levine of Hebrew University and UCLA. NASA's Cosmochemistry and Origins of Solar System programs funded this work. The U.S. Department of Energy supports the operation of the Advanced Light Source.

Source:  University of California - San Diego

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Scientists estimate total weight of plastic floating in world's oceans: Nearly 269,000 tons of plastic pollution floating in the ocean

Model results for global count density in four size classes. Model prediction of global count density (pieces km−2; see colorbar) for each of four size classes (0.33–1.00 mm, 1.01–4.75 mm, 4.76–200 mm, and >200 mm). Credit: Marcus Eriksen et al, PLoS ONE, 2014; DOI: 10.1371/journal.pone.0111913

Nearly 269,000 tons of plastic pollution may be floating in the world's oceans, according to a study published December 10, 2014 in the open-access journal PLOS ONE by Marcus Eriksen from Five Gyres Institute and colleagues.

Microplastic pollution is found in varying concentrations throughout the oceans, but estimates of the global abundance and weight of floating plastics, both micro and macroplastic, lack sufficient data to support them. To better estimate the total number of plastic particles and their weight floating in the world's oceans, scientists from six countries contributed data from 24 expeditions collected over a six-year period from 2007-2013 across all five sub-tropical gyres, coastal Australia, Bay of Bengal, and the Mediterranean Sea. The data included information about microplastics collected using nets and large plastic debris from visual surveys, which were then used to calibrate an ocean model of plastic distribution.

Based on the data and model, the authors of the study estimate a minimum of 5.25 trillion plastic particles weighing nearly 269,000 tons in the world's oceans. Large plastics appear to be abundant near coastlines, degrading into microplastics in the 5 subtropical gyres, and that the smallest microplastics were present in more remote regions, such as the subpolar gyres, which the authors did not expect. The distribution of the smallest microplastics in remote regions of the ocean may suggest that gyres act as 'shredders' of large plastic items into microplastics, after which they eject them across the ocean.

"Our findings show that the garbage patches in the middle of the five subtropical gyres are not the final resting places for the world's floating plastic trash. The endgame for micro-plastic is interactions with entire ocean ecosystems," says Marcus Eriksen, PhD, Director of Research for the 5 Gyres Institute.

Source: PLOS

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Fine particulate air pollution linked with increased autism risk

The greater the exposure a pregnant woman has to fine particulate matter, the greater the risk of their baby having autism, researchers found. Credit: © Oleg Shelomentsev / Fotolia

Women exposed to high levels of fine particulate matter specifically during pregnancy--particularly during the third trimester--may face up to twice the risk of having a child with autism than mothers living in areas with low particulate matter, according to a new study from Harvard School of Public Health (HSPH). The greater the exposure, the greater the risk, researchers found. It was the first U.S.-wide study exploring the link between airborne particulate matter and autism.

"Our data add additional important support to the hypothesis that maternal exposure to air pollution contributes to the risk of autism spectrum disorders," said Marc Weisskopf, associate professor of environmental and occupational epidemiology and senior author of the study. "The specificity of our findings for the pregnancy period, and third trimester in particular, rules out many other possible explanations for these findings."

The study appears online December 18, 2014 in Environmental Health Perspectives.

Prior studies have suggested that, in addition to genetics, exposure to airborne environmental contaminants, particularly during pregnancy and early life, may affect risk of autism. This study focused specifically on the pregnancy period.

The study population included offspring of participants living in all 50 states in Nurses' Health Study II, a cohort of more than 116,000 female U.S. nurses begun in 1989. The researchers collected data on where participants lived during their pregnancies as well as data from the U.S. Environmental Protection Agency and other sources on levels of fine particulate matter air pollution (PM2.5)--particles 2.5 microns in diameter or smaller--in locations across the U.S. The researchers identified 245 children who were diagnosed with autism spectrum disorder (ASD) and a control group of 1,522 children without ASD during the time period studied.

The researchers explored the association between autism and exposure to PM2.5 before, during, and after pregnancy. They also calculated exposure to PM2.5 during each pregnancy trimester.

Exposure to PM2.5 was significantly associated with autism during pregnancy, but not before or after, the study found. And during the pregnancy, the third trimester specifically was significantly associated with an increased risk. Little association was found between air pollution from larger-sized particles (PM10-2.5) and autism.

"The evidence base for a role for maternal exposure to air pollution increasing the risk of autism spectrum disorders is becoming quite strong," said Weisskopf. "This not only gives us important insight as we continue to pursue the origins of autism spectrum disorders, but as a modifiable exposure, opens the door to thinking about possible preventative measures."

Source: Harvard School of Public Health

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2014 Antarctic ozone hole holds steady

This image shows ozone concentrations above Antarctica on Sept. 11, 2014. Credit: NASA

The single-day maximum area was similar to that in 2013, which reached 24.0 million square kilometers (9.3 million square miles). The largest single-day ozone hole ever recorded by satellite was 29.9 million square kilometers (11.5 million square miles) on Sept. 9, 2000. Overall, the 2014 ozone hole is smaller than the large holes of the 1998-2006 period, and is comparable to 2010, 2012, and 2013.

With the increased atmospheric chlorine levels present since the 1980s, the Antarctic ozone hole forms and expands during the Southern Hemisphere spring (August and September). The ozone layer helps shield life on Earth from potentially harmful ultraviolet radiation that can cause skin cancer and damage plants.

The Montreal Protocol agreement beginning in 1987 regulated ozone depleting substances, such as chlorine-containing chlorofluorocarbons and bromine-containing halons. The 2014 level of these substances over Antarctica has declined about 9 percent below the record maximum in 2000.

"Year-to-year weather variability significantly impacts Antarctica ozone because warmer stratospheric temperatures can reduce ozone depletion," said Paul A. Newman, chief scientist for atmospheres at NASA's Goddard Space Flight Center in Greenbelt, Maryland. "The ozone hole area is smaller than what we saw in the late-1990s and early 2000s, and we know that chlorine levels are decreasing. However, we are still uncertain about whether a long-term Antarctic stratospheric temperature warming might be reducing this ozone depletion."

Scientists are working to determine if the ozone hole trend over the last decade is a result of temperature increases or chorine declines. An increase of stratospheric temperature over Antarctica would decrease the ozone hole's area. Satellite and ground-based measurements show that chlorine levels are declining, but stratospheric temperature analyses in that region are less reliable for determining long-term trends.

Scientists also found that the minimum thickness of ozone layer this year was recorded at 114 Dobson units on Sept. 30, compared to 250-350 Dobson units during the 1960s. Over the last 50 years satellite and ground-based records over Antarctica show ozone column amounts ranging from 100 to 400 Dobson units, which translates to about 1 millimeter (1/25 inch) to 5 millimeters (1/6 inch) of ozone in a layer if all of the ozone were brought down to the surface.

The ozone data come from the Dutch-Finnish Ozone Monitoring Instrument on NASA's Aura satellite and the Ozone Monitoring and Profiler Suite instrument on the NASA-NOAA Suomi National Polar-orbiting Partnership satellite. NOAA measurements at South Pole station monitor the ozone layer above that location by means of Dobson spectrophotometer and regular ozone-sonde balloon launches that record the thickness of the ozone layer and its vertical distribution. Chlorine amounts are estimated using NOAA and NASA ground measurements and observations from the Microwave Limb Sounder aboard NASA's Aura satellite.

NASA and NOAA are mandated under the Clean Air Act to monitor ozone-depleting gases and stratospheric depletion of ozone. Scientists from NASA and NOAA have been monitoring the ozone layer and the concentrations of ozone-depleting substances and their breakdown products from the ground and with a variety of instruments on satellites and balloons since the 1970s. These observations allow us to provide a continuous long-term record to track the long-term and year-to-year evolution of ozone amounts.

Source:  NASA/Goddard Space Flight Center

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Easy measurement of the effect of fine dust

The Karlsruhe Exposure System is compact and can measure fine dust concentrations directly at the location of pollution. Credit: VITROCELL Systems GmbH

Fine dusts from industry, traffic, and households are omnipresent. Still, they are difficult to capture by reliable medical measurements. KIT researchers have now developed an exposure system, by means of which biological cells are exposed to fine dust-loaded air flows in an exact and reproducible manner. Using this system, it is possible to collect data on the adverse impact of fine dusts of variable sources in a rapid and inexpensive manner and without animal experiments being needed. In cooperation with the industry partner Vitrocell, a marketable product has been developed.

"Fine dusts may be carbon black from diesel engines, sea salt on the coast, natural dusts, or intermediate products of chemical industry," Dr. Hanns-Rudolf Paur and Sonja Mülhopt of Karlsruhe Institute of Technology explain. All dust grains smaller than 10 µm, i.e. one hundredth of a millimeter, are considered to be fine dust irrespective of their chemical composition. Dust particles smaller than 10 µm easily pass the upper respiratory tract of man. "They deposit in the pulmonary alveoli and may damage the lungs due to their chemical or physical properties."

To study the effects in detail, lung cells and fine dust have to be brought together in a realistic environment. Ultimately, the processes taking place in the human body from the nose to the lungs have to be reproduced. For this purpose, the air containing the fine dust is heated up to body temperature by the Karlsruhe Exposure System. The air flow is provided with about 85% humidity and reduced to the air flow rate of the lungs. For a long-term measurement series, these conditions have to be maintained exactly and reproducibly. Finally, the particle flow passes lung cell cultures cultivated with nutrient medium. 

Depending on the type of fine dust, these cultures subsequently show symptoms of inflammation, oxidation stress, or membrane damage. In parallel, the deposited particle dose is recorded by means of a precision balance.

The new Exposure System is much closer to reality than previous methods that collected fine dust from air or exhaust gas and stirred it into the nutrient liquid. At the same time, the Exposure System works more rapidly for many applications and is cheaper than a study based on animal experiments. Thanks to its compactness, the Karlsruhe Exposure System can also be used for measurements at the place of fine dust development or pollution. "The limitations of conventional methods were overcome by the close, interdisciplinary cooperation of biologists and process engineers at KIT," the Head of the project, Sonja Mülhopt, says. "With the Karlsruhe Exposure System, we now have a technology that will improve the protection of the environment and mankind."

"Research at KIT was the basis of a process with a high industry potential," Tobias Krebs of the company Vitrocell Systems (Waldkirch) says. "Together, we now plan to commercialize this product." The impact of fine dusts plays an important role in fundamental research as well as in many areas of application. According to the EU Directive on Chemicals REACH, chemical industry is obliged to classify its products in various hazard categories. 

Manufacturers of lung medicine, such as asthma sprays, are now enabled to test new substances in a close-to-reality manner. New and old biomass fuels may also be relevant fine dust sources.

Source:  Karlsruhe Institute of Technology

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Fracking and pollution: Technology-dependent emissions of gas extraction in the US

The KIT measurement instrument on board of a minivan directly measures atmospheric emissions on site with a high temporal resolution.
Credit: Photo: F. Geiger/KIT

Not all boreholes are the same. Scientists of the Karlsruhe Institute of Technology (KIT) used mobile measurement equipment to analyze gaseous compounds emitted by the extraction of oil and natural gas in the USA. For the first time, organic pollutants emitted during a fracking process were measured at a high temporal resolution using a vapor capture system. The highest values measured by this process exceeded typical mean values in urban air by a factor of about one thousand, as was reported in the ACP journal.

Emission of trace gases by oil and gas fields was studied by the KIT researchers in the USA (Utah and Colorado) together with US institutes. Background concentrations and the waste gas plumes of single extraction plants and fracking facilities were analyzed. The air quality measurements of several weeks duration took place under the "Uintah Basin Winter Ozone Study" coordinated by the National Oceanic and Atmospheric Administration (NOAA).

The KIT measurements focused on health-damaging aromatic hydrocarbons in air, such as carcinogenic benzene. Maximum concentrations were determined in the waste gas plumes of boreholes. Some extraction plants emitted up to about a hundred times more benzene than others. The highest values of some milligrams of benzene per cubic meter air were measured downstream of an open fracking facility, where returning drilling fluid is stored in open tanks and basins. Much better results were reached by oil and gas extraction plants and plants with closed production processes. In Germany, benzene concentration at the workplace is subject to strict limits: The Federal Emission Control Ordinance gives an annual benzene limit of five micrograms per cubic meter for the protection of human health, which is smaller than the values now measured at the open fracking facility in the US by a factor of about one thousand. The researchers published the results measured in the journal Atmospheric Chemistry and Physics ACP.

"Characteristic emissions of trace gases are encountered everywhere. These are symptomatic of gas and gas extraction. But the values measured for different technologies differ considerably," Felix Geiger of the Institute of Meteorology and Climate Research (IMK) of KIT explains. He is one of the first authors of the study. By means of closed collection tanks and so-called vapor capture systems, for instance, the gases released during operation can be collected and reduced significantly.

"The gas fields in the sparsely populated areas of North America are a good showcase for estimating the range of impacts of different extraction and fracking technologies," explains Professor Johannes Orphal, Head of IMK. "In the densely populated Germany, framework conditions are much stricter and much more attention is paid to reducing and monitoring emissions."

Fracking is increasingly discussed as a technology to extract fossil resources from unconventional deposits. Hydraulic breaking of suitable shale stone layers opens up the fossil fuels stored there and makes them accessible for economically efficient use. For this purpose, boreholes are drilled into these rock formations. Then, they are subjected to high pressure using large amounts of water and auxiliary materials, such as sand, cement, and chemicals. The oil or gas can flow to the surface through the opened microstructures in the rock. Typically, the return flow of the aqueous fracking liquid with the dissolved oil and gas constituents to the surface lasts several days until the production phase proper of purer oil or natural gas. This return flow is collected and then reused until it finally has to be disposed of. Air pollution mainly depends on the treatment of this return flow at the extraction plant. In this respect, currently practiced fracking technologies differ considerably. For the first time now, the resulting local atmospheric emissions were studied at a high temporary resolution. Based on the results, emissions can be assigned directly to the different plant sections of an extraction plant. For measurement, the newly developed, compact, and highly sensitive instrument, a so-called proton transfer reaction mass spectrometer (PTR-MS), of KIT was installed on board of a minivan and driven closer to the different extraction points, the distances being a few tens of meters. In this way, the waste gas plumes of individual extraction sources and fracking processes were studied in detail.

Source: Karlsruhe Institute of Technology

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Switching to vehicles powered by electricity from renewables could save lives

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. Credit: © Dmitry Vereshchagin / Fotolia

Driving vehicles that use electricity from renewable energy instead of gasoline could reduce the resulting deaths due to air pollution by 70 percent. This finding comes from a new life cycle analysis of conventional and alternative vehicles and their air pollution-related public health impacts, published Monday, Dec. 15, 2014, in the Proceedings of the National Academy of Sciences.

The study also shows that switching to vehicles powered by electricity made using natural gas yields large health benefits. Conversely, vehicles running on corn ethanol or vehicles powered by coal-based or "grid average" electricity are worse for health; switching from gasoline to those fuels would increase the number of resulting deaths due to air pollution by 80 percent or more.

"These findings demonstrate the importance of clean electricity, such as from natural gas or renewables, in substantially reducing the negative health impacts of transportation," said Chris Tessum, co-author on the study and a researcher in the Department of Civil, Environmental, and Geo- Engineering in the University of Minnesota's College of Science and Engineering.

The University of Minnesota team estimated how concentrations of two important pollutants -- particulate matter and ground-level ozone -- change as a result of using various options for powering vehicles. Air pollution is the largest environmental health hazard in the U.S., in total killing more than 100,000 people per year. Air pollution increases rates of heart attack, stroke, and respiratory disease.

The authors looked at liquid biofuels, diesel, compressed natural gas, and electricity from a range of conventional and renewable sources. Their analysis included not only the pollution from vehicles, but also emissions generated during production of the fuels or electricity that power them. With ethanol, for example, air pollution is released from tractors on farms, from soils after fertilizers are applied, and to supply the energy for fermenting and distilling corn into ethanol.

"Our work highlights the importance of looking at the full life cycle of energy production and use, not just at what comes out of tailpipes," said Bioproducts and Biosystems Engineering Assistant Professor Jason Hill, co-author of the study. "We greatly underestimate transportation's impacts on air quality if we ignore the upstream emissions from producing fuels or electricity."

The researchers also point out that whereas recent studies on life cycle environmental impacts of transportation have focused mainly on greenhouse gas emissions, it is also important to consider air pollution and health. Their study provides a unique look at where life cycle emissions occur, how they move in the environment, and where people breathe that pollution. Their results provide unprecedented detail on the air quality-related health impacts of transportation fuel production and use.

"Air pollution has enormous health impacts, including increasing death rates across the U.S.," said Civil, Environmental and Geo- Engineering Associate Professor Julian Marshall, co-author on this study. "This study provides valuable new information on how some transportation options would improve or worsen those health impacts."

Source: University of Minnesota

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NASA's CATS eyes clouds, smoke and dust from the space station

The interactions between clouds and aerosols are illustrated in this image, taken by retired astronaut Chris Hadfield onboard the International Space Station. It shows contrails produced by aircraft (bright streaks) over the ocean. Credit: NASA/Chris Hadfield

Turn on any local TV weather forecast and you can get a map of where skies are blue or cloudy. But for scientists trying to figure out how clouds affect Earth's environment, what's happening inside that shifting cloud cover is critical and hard to see.

To investigate the layers and composition of clouds and tiny airborne particles like dust, smoke and other atmospheric aerosols, , scientists at NASA's Goddard Space Flight Center in Greenbelt, Maryland have developed an instrument called the Cloud-Aerosol Transport System, or CATS. The instrument, which launches to the International Space Station in December 2014, will explore new technologies that could also be used in future satellite missions.

From space, streaks of white clouds can be seen moving across Earth's surface. Other tiny solid and liquid particles called aerosols are also being transported around the atmosphere, but these are largely invisible to our eyes. Aerosols are both natural and man-made, and include windblown desert dust, sea salt, smoke from fires, sulfurous particles from volcanic eruptions, and particles from fossil fuel combustion.

Currently, scientists get a broad picture of clouds and air quality conditions in the atmosphere and generate air quality forecasts by combining satellite, aircraft, and ground-based data with sophisticated computer models. However, most datasets do not provide information about the layered structure of clouds and aerosols.

CATS will provide data about aerosols at different levels of the atmosphere. The data are expected to improve scientists' ability to track different cloud and aerosol types throughout the atmosphere. These datasets will be used to improve strategic and hazard-warning capabilities of events in near real-time, such as tracking plumes from dust storms, volcanic eruptions, and wildfires. The information could also feed into climate models to help understand the effects of clouds and aerosols on Earth's energy balance.

Clouds and aerosols reflect and absorb energy from the sun in a complex way. For example, when the sun's energy reaches the top of the atmosphere, clouds can reflect incoming sunlight, cooling Earth's surface. However, clouds can also absorb heat emitted from Earth and re-radiate it back down, warming the surface. The amount of warming or cooling is heavily dependent on the height, thickness, and structure of clouds in the atmosphere above.

"Clouds are one of the largest uncertainties in predicting climate change," said Matt McGill, principal investigator and payload developer for CATS at Goddard. "For scientists to create more accurate models of Earth's current and future climate, they'll have to include more accurate representations of clouds."

That's where a new instrument like CATS comes in. CATS is a lidar -- similar to a radar, but instead of sending out sound, lidars use light. CATS will send a laser pulse through the atmosphere towards a distant object like a cloud droplet or aerosol particle. Once the energy reaches the object, some of the energy is reflected back to the lidar receiver. Scientists can calculate the distance between the instrument and the object, based on the time it takes the energy to return to the receiver, thereby determining the altitudes of cloud and aerosol layers. The intensity of this return pulse also allows scientists to infer other properties, such as the composition of clouds, and the abundance and sizes of aerosols,.

In 2006 NASA launched the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations, or CALIPSO, spacecraft -- a joint mission between NASA and France's space agency, the Centre National d'Études Spatiales. CALIPSO carries a lidar that provides vertical distributions and properties of clouds and aerosols along a flight track. However, the CALIPSO lidar has exceeded its three-year prime mission and has been using its backup laser since 2009.

A unique opportunity to continue gathering this type of data presented itself in 2011 when the International Space Station Progam's NASA Research Office offered scientists at Goddard a mounting location aboard the space station for a new lidar instrument -- CATS, and provided the funding for its construction.

Designed to operate for at least six months, CATS has a goal of operating for three years. With beams at three wavelengths (1064, 532, and 355 nanometers), CATS will be used to derive a variety of properties of cloud and aerosol layers. These properties include layer height, layer thickness, and at least coarse information on the type of aerosols and cloud in various atmospheric layers.

CATS will orbit aboard the space station, which flies at an altitude between 230 miles (375 kilometers) and 270 miles (435 kilometers) above Earth's surface at a 51-degree inclination. This unique orbit path will allow the CATS instrument to observe locations at different times of day and allow scientists to study day-to-night changes in cloud and aerosol effects from space.

Studying clouds and aerosols won't just help scientists study the climate, it's also a chance to investigate air quality and how atmospheric particles affect daily life. That can range from volcano ash plumes, to dust storms, to pollution outbreaks, to wildfires, like the California Rim Fire in September 2013 that choked Yosemite National Park during the busy Labor Day weekend. These particles pose health risks to populations, especially to the medically vulnerable, By infusing CATS data directly into aerosol models, data from CATS can make a difference in tracking and responding to impacts of similar events in the future.

Source:  NASA/Goddard Space Flight Center

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Updating air pollution measurement methods

Launching a natural research experiment in Kathmandu, Nepal, this month using advanced monitoring methods to assess health risk from air pollution, environmental health scientist Rick Peltier at the University of Massachusetts Amherst hopes to demonstrate for the first time in a real-world setting that air pollution can and should be regulated based on toxicology variables rather than simply on the volume of particles in the air.

Recent technological advances in air quality measurement methods now make it possible and practical to monitor air pollution in a much more sophisticated way than before, Peltier says. Researchers now use X-ray fluorescence spectrometry to measure air pollution metal content, ion chromatography to identify other chemicals and other tactics to assess organic and elemental carbon levels.

Peltier says, "We're interested in how air pollution directly affects health. The current regulatory method doesn't take into account the relative toxicity of components, that is the specific chemical makeup of the air we breathe. There has been a void in the science in this field. But with this experiment, for the first time we'll have biological measurements coupled with high-quality air pollution measurements in a cohort of traffic police exposed to extreme levels of pollution."

At present, the Environmental Protection Agency monitors air quality components every three days at 350 stations across the United States, but there are no such sites in Nepal. Particulates are an important signature of traffic. A poor air quality day in Los Angeles may see 40-50 micrograms of particulates per cubic meter, Peltier says, while in Kathmandu the level can be 800-900, or about 20 times worse.

Ethically, the environmental scientist adds, it would be impossible to expose people to such pollution levels in a laboratory-based experiment, and ambient levels such as those typically observed in Kathmandu are never routinely encountered anywhere in the United States. Peltier and colleagues' study will take advantage of the fact that the traffic officers already are exposed to high air pollution levels in their normal workday.

Funded by a multinational partnership led by UMass Amherst and including the Himalayan region's Intergovernmental Centre for Integrated Mountain Development (ICIMOD) and the Institute for Advanced Sustainability Studies in Potsdam, Germany, the investigation will follow a cohort of 32 traffic control officers in Kathmandu during two seasons: Cold, dry winter from this month into March, with a second study in the hot, rainy monsoon season from June to August, when air pollution levels are lower.

Peltier observes that Nepal's capital city region has poor air quality because two-stroke gasoline and diesel engines, high pollutant emitters, are common. Also, people heat their homes with coal and kerosene and routinely burn garbage and tires outdoors. For the 3 million inhabitants this poses substantial, demonstrable health risks.

"Unfortunately, the Kathmandu metropolitan area has quite poor air quality, and it's in a valley so it is a persistent problem," he adds. "We hypothesize that toxicity is related to the chemical components of pollution. We know this is true in a Petri dish, but now we'll be able to measure it in study subjects."
Participants are 16 men and 16 women, 25 to 35 years old who have similar education and income levels. For a six-day work week, each will carry a small waist pack containing research-grade, solar-powered portable air samplers. The filters will be collected for airborne metals, ions, organic carbon and black carbon analysis. The experiment will include an intervention component, as well: For half of each study week, participants will wear high-quality, particle-filtering face masks that greatly reduce air pollution exposure.

In addition to the air filters, researchers will collect blood samples and ask the traffic officers to use a spirometer several times a day to assess lung function. Their location, activity and electrocardiogram will be continuously measured in both conditions: Breathing polluted air with and without protective face masks.

Air quality samples and the health measurement data will be analyzed at UMass Amherst and compared between the different exposure conditions. Peltier and his postdoctoral fellow Kabindra Shakya will collaborate with researcher Arnico Panday of ICIMOD, Kathmandu, which along with UMass Amherst supported the work, plus Maheswar Rupakheti of the sustainability institute in Potsdam.

Source: University of Massachusetts 

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Carbon dioxide converted into a valuable resource

Arshe Said, postgraduate researcher at Aalto University, operating a pilot plant that converts CO2 and slag into Precipitated Calcium Carbonate (PCC). Credit: Image courtesy of Aalto University

Researchers at Aalto University have opened a pilot plant that converts CO2 and slag, the by-product of steel manufacturing, into a valuable mineral product. The product, Precipitated Calcium Carbonate (PCC), is used in e.g. plastics, papers, rubbers and paints. The innovative plant represents the next stage prior commercialization of a new process that consumes CO2 in order to convert a low-value by-product into a highly valuable resource for industry.

The potential economic and environmental benefits of this new technology are significant. "We are turning the industrial solid by-product from steel-manufacturing into a product which is 50 times more valuable," says Arshe Said, a postgraduate researcher at Aalto University. "Also, this process actually consumes CO2 and acts as a CO2 sink which benefits the environment greatly."

Current methods of PCC production require burning large amounts of limestone. "The conventional method involves large mining activities and has high CO2 emissions," points out Sanni Eloneva, D.Sc. (Tech).

Carbon intensive manufacturing industries are coming under increasing pressure from bodies such as the EU to reduce greenhouse gas emissions. "We believe this pilot plant will help to efforts by these industries to conform with government imposed emissions and waste targets," explains Professor Mika Järvinen.

In 2010, 13% of the total steel slag produced in Europe (16 Mt) went to the landfill. "In theory, if all the calcium in this steel slag could be recovered, approximately 13 Mt PCC/year could be produced, simultaneously sequestering nearly 6 Mt CO2/year," Järvinen continues.

The highly promising new technology also has other potential advantages. "We are currently investigating the possibility of extracting other valuable materials from the slag after the extraction of calcium," says Said.

The pilot PCC plant is now running in Otaniemi campus of Aalto University. The method used in the pilot is based on the patent owned by Aalto University Foundation together with Åbo Akademi and Rautaruukki Oyj (now part of SSAB).

Source:  Aalto University

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The Whiter clouds could mean wetter land

White clouds as seen from above. One proposed emergency fix to halt global warming is to seed clouds over the ocean to make them more reflective, reducing the solar radiation absorbed by the Earth. But the scheme could also change global rainfall patterns, raising concerns of water shortages on land. Credit: iStockphoto/Tammy Bryngelson

One proposed emergency fix to halt global warming is to seed clouds over the ocean to make them more reflective, reducing the solar radiation absorbed by the Earth. But the scheme could also change global rainfall patterns, raising concerns of water shortages on land. A new study by the Carnegie Institution, in collaboration with the Indian Institute of Science, suggests that altered atmospheric circulation under the scheme in fact could increase monsoonal rains and cause the continents to become wetter, not drier, on average.

Whitening clouds over the ocean to reflect sunlight is one of several geoengineering schemes proposed to counter global warming. The whitening would be accomplished by reducing the size of the water droplets making up the clouds. "Rain clouds, which have big droplets, tend to be grey and absorb sunlight, whereas clouds with smaller droplets tend to be white and fluffy and reflect more sunlight to space," says co-author Ken Caldeira of the Carnegie Institution's Department of Global Ecology. "In practice this could be done by shooting a fine spray of seawater high into the air, where the tiny salt particles would create condensation nucleii to form small cloud droplets."

To test the climate consequences of doing this, Caldeira and his coauthors* used a computer simulation of the global climate system in which atmospheric carbon dioxide concentrations were set at approximately twice that of present day. Cloud droplets over the oceans in the model were reduced in size to make the clouds more reflective. Clouds over land were unaltered. As expected, the whitened clouds reflected more solar radiation and offset the warming effect of the high carbon dioxide levels.

What surprised the researchers, however, was that the model showed that the oceanic clouds caused the land surface to become cooler and wetter on average. In previous climate simulations diminishing solar radiation by geoengineering had reduced precipitation on land. "The drying of the continents has been a major concern with regard to geoengineering," says Caldeira. But in the model the runoff from the continents increased by 7.5% globally, with the effect being strongest in the tropics.

The researchers concluded that the increased precipitation over land was driven by changes in air circulation, similar to the monsoonal pattern that determines rainfall in parts of Asia. "Monsoons occur when air masses over land are warmer than air masses over the ocean, and this draws in cool, moist air from over the ocean which then drops rain over the land," says Caldeira. In the simulations, the reflective oceanic clouds preferentially cooled the air over the oceans relative to land, setting up a monsoonal air flow.

Caldeira stresses that their study, in which all marine clouds worldwide were uniformly whitened, cannot be used to predict the geographic patterns of rainfall that might develop as a result of geoengineering. "In real life, there are only certain parts of the ocean in which you could make the cloud droplets smaller," he says. Areas downwind of land, such as off the east coast of the United States, are already laden with particles of dust and pollution, so adding more particles will not significantly change cloud cover. "An actual deployment would be much patchier than in our study, and the result would therefore be somewhat different. But our basic result calls into question previous assumptions about the impact of this geoengineering scheme. It merits further investigation."

Source: Carnegie Institution

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