Graphene Is Strongest Material in the World Even with Defects

Graphene remains the strongest material ever measured and, as Professor Hone once put it, so strong that "it would take an elephant, balanced on a pencil, to break through a sheet of graphene the thickness of Saran Wrap.” —Illustration by Andrew Shea for Columbia Engineering

In a new study, published in Science May 31, 2013, Columbia Engineering researchers demonstrate that graphene, even if stitched together from many small crystalline grains, is almost as strong as graphene in its perfect crystalline form. This work resolves a contradiction between theoretical simulations, which predicted that grain boundaries can be strong, and earlier experiments, which indicated that they were much weaker than the perfect lattice.

Graphene consists of a single atomic layer of carbon, arranged in a honeycomb lattice. “Our first Science paper, in 2008, studied the strength graphene can achieve if it has no defects—its intrinsic strength,” says James Hone, professor of mechanical engineering, who led the study with Jeffrey Kysar, professor of mechanical engineering. “But defect-free, pristine graphene exists only in very small areas. Large-area sheets required for applications must contain many small grains connected at grain boundaries, and it was unclear how strong those grain boundaries were. This, our second Science paper, reports on the strength of large-area graphene films grown using chemical vapor deposition (CVD), and we’re excited to say that graphene is back and stronger than ever.”

The study verifies that commonly used methods for post-processing CVD-grown graphene weaken grain boundaries, resulting in the extremely low strength seen in previous studies. The Columbia Engineering team developed a new process that prevents any damage of graphene during transfer. “We substituted a different etchant and were able to create test samples without harming the graphene,” notes the paper’s lead author, Gwan-Hyoung Lee, a postdoctoral fellow in the Hone lab. “Our findings clearly correct the mistaken consensus that grain boundaries of graphene are weak. This is great news because graphene offers such a plethora of opportunities both for fundamental scientific research and industrial applications.”

                                              Profs. James Hone and Jeffrey Kysar
In its perfect crystalline form, graphene (a one-atom-thick carbon layer) is the strongest material ever measured, as the Columbia Engineering team reported in Science in 2008—so strong that, as Hone observed, “it would take an elephant, balanced on a pencil, to break through a sheet of graphene the thickness of Saran Wrap.” For the first study, the team obtained small, structurally perfect flakes of graphene by mechanical exfoliation, or mechanical peeling, from a crystal of graphite. But exfoliation is a time-consuming process that will never be practical for any of the many potential applications of graphene that require industrial mass production.

Currently, scientists can grow sheets of graphene as large as a television screen by using chemical vapor deposition (CVD), in which single layers of graphene are grown on copper substrates in a high-temperature furnace. One of the first applications of graphene may be as a conducting layer in flexible displays.

“But CVD graphene is ‘stitched’ together from many small crystalline grains—like a quilt—at grain boundaries that contain defects in the atomic structure,” Kysar explains. “These grain boundaries can severely limit the strength of large-area graphene if they break much more easily than the perfect crystal lattice, and so there has been intense interest in understanding how strong they can be.”

The Columbia Engineering team wanted to discover what was making CVD graphene so weak. In studying the processing techniques used to create their samples for testing, they found that the chemical most commonly used to remove the copper substrate also causes damage to the graphene, severely degrading its strength.

WATCH VIDEO
Click on the Video to watch Prof. James Hone take us on a tour of his synthesis lab in the Northwest Corner Building, where he grows graphene and nanotubes.

Their experiments demonstrated that CVD graphene with large grains is exactly as strong as exfoliated graphene, showing that its crystal lattice is just as perfect. And, more surprisingly, their experiments also showed that CVD graphene with small grains, even when tested right at a grain boundary, is about 90% as strong as the ideal crystal.

“This is an exciting result for the future of graphene, because it provides experimental evidence that the exceptional strength it possesses at the atomic scale can persist all the way up to samples inches or more in size,” says Hone. “This strength will be invaluable as scientists continue to develop new flexible electronics and ultrastrong composite materials.”

Strong, large-area graphene can be used for a wide variety of applications such as flexible electronics and strengthening components—potentially, a television screen that rolls up like a poster or ultrastrong composites that could replace carbon fiber. Or, the researchers speculate, a science fiction idea of a space elevator that could connect an orbiting satellite to Earth by a long cord that might consist of sheets of CVD graphene, since graphene (and its cousin material, carbon nanotubes) is the only material with the high strength-to-weight ratio required for this kind of hypothetical application.

The team is also excited about studying 2D materials like graphene. “Very little is known about the effects of grain boundaries in 2D materials,” Kysar adds. “Our work shows that grain boundaries in 2D materials can be much more sensitive to processing than in 3D materials. This is due to all the atoms in graphene being surface atoms, so surface damage that would normally not degrade the strength of 3D materials can completely destroy the strength of 2D materials. However with appropriate processing that avoids surface damage, grain boundaries in 2D materials, especially graphene, can be nearly as strong as the perfect, defect-free structure.”

The study was supported by grants from the Air Force Office of Scientific Research and the National Science Foundation.

—by Holly Evarts

Source: Columbia University

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Grad Student Solves 30-Year-Old Physics Problem

                    Emilie Huffman, second year PhD student in physics. Credit: Duke University

Sometimes an age-old question just needs a fresh set of eyes.

That was the case in Duke’s physics department, where a graduate student and professor recently resolved a calculating dilemma that has vexed computational physicists for decades.

Emilie Huffman is a second-year PhD student from Charlotte, North Carolina. Last spring she began working with Shailesh Chandrasekharan, an associate professor and the director of graduate studies in physics, on what’s known as a sign problem.

Chandrasekharan is a theoretical nuclear and particle physicist who specializes in solving sign problems, which arise when one uses certain computational algorithms to calculate the behavior of large numbers of particles called fermions.

“Almost all the matter we know of are made with fermions,” Chandrasekharan said. “As building blocks of matter, it’s very important to be able to do calculations with them.”

But calculations of such complexity get tricky, and sign problems make it easy for wrong results to surface.

“It’s a very broad problem that affects almost all fields of physics involving quantum mechanics with strong correlations, where Monte Carlo methods are essential to perform calculations,” Chandrasekharan said.

Some in the field have simply moved on since the 1980s, leaving interesting questions plagued by sign problems unexplored. Other scientists have found workarounds and approximations. Very few, including Chandrasekharan, have tried to figure out solutions through the years. Huffman began work to expand on one of her advisor’s solutions, involving a grouping concept called fermion bags, and apply them to a new class of problems.

“She finally figured out a nice formula,” Chandrasekharan said. “Although the formula is quite simple and elegant, I couldn’t guess it.”

“In physics, often there’s a truth, and if you’re hitting on the right truth, everything starts falling into place.” Chandrasekharan says that’s what happened when he began applying Huffman’s formula to a class of problems.

Their paper appeared recently in the journal Physical Review B’s Rapid Communications.

“Now that I have a solution, I can begin to apply it,” Huffman said. Starting with condensed matter physics, Huffman plans to apply her solution to various questions that have been stymied by sign problems. “I can use this solution to study properties of graphene,” she said, referring to the single-layer carbon that has been touted as the strongest material in the world. Many puzzles remain in the field, especially involving multi-layer graphene sheets.

Wherever she turns her attention next, it’s clear Huffman has a promising career ahead.

Citation: “Solution to sign problems in half-filled spin-polarized electronic systems,” Emilie Huffman and Shailesh Chandrasekharan. Physical Review B Rapid Communications, March 12, 2014. DOI: 10.1103/PhysRevB.89.111101.

Source: Duke University

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String field theory could be the foundation of quantum mechanics: Connection could be huge boost to string theory

Artist's abstraction (stock illustration). Credit: © agsandrew / Fotolia

Two USC researchers have proposed a link between string field theory and quantum mechanics that could open the door to using string field theory -- or a broader version of it, called M-theory -- as the basis of all physics.

"This could solve the mystery of where quantum mechanics comes from," said Itzhak Bars, USC Dornsife College of Letters, Arts and Sciences professor and lead author of the paper.

Bars collaborated with Dmitry Rychkov, his Ph.D. student at USC. The paper was published online on Oct. 27 by the journal Physics Letters.

Rather than use quantum mechanics to validate string field theory, the researchers worked backwards and used string field theory to try to validate quantum mechanics.

In their paper, which reformulated string field theory in a clearer language, Bars and Rychov showed that a set of fundamental quantum mechanical principles known as "commutation rules'' may be derived from the geometry of strings joining and splitting.

"Our argument can be presented in bare bones in a hugely simplified mathematical structure," Bars said. "The essential ingredient is the assumption that all matter is made up of strings and that the only possible interaction is joining/splitting as specified in their version of string field theory."

Physicists have long sought to unite quantum mechanics and general relativity, and to explain why both work in their respective domains. First proposed in the 1970s, string theory resolved inconsistencies of quantum gravity and suggested that the fundamental unit of matter was a tiny string, not a point, and that the only possible interactions of matter are strings either joining or splitting.

Four decades later, physicists are still trying to hash out the rules of string theory, which seem to demand some interesting starting conditions to work (like extra dimensions, which may explain why quarks and leptons have electric charge, color and "flavor" that distinguish them from one another).

At present, no single set of rules can be used to explain all of the physical interactions that occur in the observable universe.

On large scales, scientists use classical, Newtonian mechanics to describe how gravity holds the moon in its orbit or why the force of a jet engine propels a jet forward. Newtonian mechanics is intuitive and can often be observed with the naked eye.

On incredibly tiny scales, such as 100 million times smaller than an atom, scientists use relativistic quantum field theory to describe the interactions of subatomic particles and the forces that hold quarks and leptons together inside protons, neutrons, nuclei and atoms.

Quantum mechanics is often counterintuitive, allowing for particles to be in two places at once, but has been repeatedly validated from the atom to the quarks. It has become an invaluable and accurate framework for understanding the interactions of matter and energy at small distances.

Quantum mechanics is extremely successful as a model for how things work on small scales, but it contains a big mystery: the unexplained foundational quantum commutation rules that predict uncertainty in the position and momentum of every point in the universe.

"The commutation rules don't have an explanation from a more fundamental perspective, but have been experimentally verified down to the smallest distances probed by the most powerful accelerators. Clearly the rules are correct, but they beg for an explanation of their origins in some physical phenomena that are even deeper," Bars said.

The difficulty lies in the fact that there's no experimental data on the topic -- testing things on such a small scale is currently beyond a scientist's technological ability.

Source: University of Southern California

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Charged graphene gives DNA a stage to perform molecular gymnastics

DNA interacts with charged graphene and contorts into sequence-specific shapes when the charge is changed. Credit: Photo courtesy Alek Aksimentiev

When Illinois researchers set out to investigate a method to control how DNA moves through a tiny sequencing device, they did not know they were about to witness a display of molecular gymnastics.

Fast, accurate and affordable DNA sequencing is the first step toward personalized medicine. Threading a DNA molecule through a tiny hole, called a nanopore, in a sheet of graphene allows researchers to read the DNA sequence; however, they have limited control over how fast the DNA moves through the pore. In a new study published in the journal Nature Communications, University of Illinois physics professor Aleksei Aksimentiev and graduate student Manish Shankla applied an electric charge to the graphene sheet, hoping that the DNA would react to the charge in a way that would let them control its movement down to each individual link, or nucleotide, in the DNA chain.

"Ideally, you would want to step the DNA through the nanopore one nucleotide at a time," said Aksimentiev. "Take a measurement and then have another nucleotide in the sensing hole. That's the goal, and it hasn't been realized yet. We show that, to some degree, we can control the process by charging the graphene."

The researchers found that a positive charge in the graphene speeds up DNA movement through the nanopore, while a negative charge stops the DNA in its tracks. However, as they watched, the DNA seemed to dance across the graphene surface, pirouetting into shapes they had never seen, specific to the sequence of the DNA nucleotides.

"It reminds me of Swan Lake," Aksimentiev said. "It's very acrobatic. We were very surprised by the variety of DNA conformations that we can observe at the surface of graphene when we charge it. There is one sequence that starts out laying down on the surface, and when we change the charge, they all tilt on the side like they are doing a one-armed push-up. Then we also have nucleotides that would lay back, or go up like a ballerina en pointe."

Aksimentiev hypothesizes that the conformations are so different and so specific to the sequence because each nucleotide has a slightly different distribution of electrons, the negatively charged parts of the atoms. There is even a visible difference when a nucleotide is methylated, a tiny chemical change that can turn a gene on or off.

By switching the charge in the graphene, the researchers can control not only the DNA's motion through the pore, but also the shape the DNA contorts into.

"Because it's reversible, we can force it to adopt one conformation and then force it to go back. That's why we call it gymnastics," Aksimentiev said.

The researchers extensively used the Blue Waters supercomputer at the National Center for Supercomputing Applications, housed at the University of Illinois. They mapped each individual atom in the complex DNA molecule and ran numerous simulations of many different DNA sequences. Supercomputing power was essential to carrying out the work, Aksimentiev said.

"This is a really computationally intensive project," he said. "Having access to Blue Waters was essential because with the sheer number of simulations, we would not have been able to finish them. It would have taken too long."

The next step is to combine a charged nanopore setup with a sensor to build a DNA sequencing device that would incorporate both motion control and nucleotide recognition. The researchers also hope to explore the unexpected conformational changes for insights into epigenetics, the field that studies how genes are expressed and moderated.

"DNA is much more complicated than just a double helix. It's a complex molecule that has many properties, and we are still uncovering them," Aksimentiev said.

Video animation of DNA dancing as the graphene charge changes:


Source: University of Illinois at Urbana-Champaign

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A new step towards using graphene in electronic applications

(A) This image is a diagram of molecular precursors, the resulting graphene nanoribbons and the heterostructured ones. (B) Tunnel microscopy images of the heterostructures synthesized on gold surfaces. Credit: UPV/EHU

Few materials have received as much attention from the scientific world or have raised so many hopes with a view to their potential deployment in new applications as graphene has. This is largely due to its superlative properties: it is the thinnest material in existence, almost transparent, the strongest, the stiffest and at the same time the most strechable, the best thermal conductor, the one with the highest intrinsic charge carrier mobility, plus many more fascinating features. Specifically, its electronic properties can vary enormously through its confinement inside nanostructured systems, for example. That is why ribbons or rows of graphene with nanometric widths are emerging as tremendously interesting electronic components. On the other hand, due to the great variability of electronic properties upon minimal changes in the structure of these nanoribbons, exact control on an atomic level is an indispensable requirement to make the most of all their potential.

The lithographic techniques used in conventional nanotechnology do not yet have such resolution and precision. In the year 2010, however, a way was found to synthesise nanoribbons with atomic precision by means of the so-called molecular self-assembly. 

Molecules designed for this purpose are deposited onto a surface in such a way that they react with each other and give rise to perfectly specified graphene nanoribbons by means of a highly reproducible process and without any other external mediation than heating to the required temperature. In 2013 a team of scientists from the University of Berkeley and the Centre for Materials Physics (CFM), a mixed CSIC (Spanish National Research Council) and UPV/EHU (University of the Basque Country) centre, extended this very concept to new molecules that were forming wider graphene nanoribbons and therefore with new electronic properties. This same group has now managed to go a step further by creating, through this self-assembly, heterostructures that blend segments of graphene nanoribbons of two different widths.

The forming of heterostructures with different materials has been a concept widely used in electronic engineering and has enabled huge advances to be made in conventional electronics. "We have now managed for the first time to form heterostructures of graphene nanoribbons modulating their width on a molecular level with atomic precision. What is more, their subsequent characterisation by means of scanning tunnelling microscopy and spectroscopy, complemented with first principles theoretical calculations, has shown that it gives rise to a system with very interesting electronic properties which include, for example, the creation of what are known as quantum wells," pointed out the scientist Dimas de Oteyza, who has participated in this project. This work, the results of which are being published this very week in the journal Nature Nanotechnology, therefore constitutes a significant success towards the desired deployment of graphene in commercial electronic applications.

Dr Dimas G. de Oteyza, who was previously at Berkeley and at the CFM, is currently working at the Donostia International Physics Center (DIPC) as a Fellow Gipuzkoa.

Source: University of the Basque Country

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The simplest element: Turning hydrogen into 'graphene'

This image is a comparison of the carbon compound graphene with a similar hydrogen-based structure synthesized by Carnegie scientists. Credit: Carneige's Ivan Naumov and Russell Hemley

New work from Carnegie's Ivan Naumov and Russell Hemley delves into the chemistry underlying some surprising recent observations about hydrogen, and reveals remarkable parallels between hydrogen and graphene under extreme pressures. Their work is the cover story in the December issue of Accounts of Chemical Research.

Hydrogen is the most-abundant element in the cosmos. With only a single electron per atom, it is deceptively simple. As a result, hydrogen has been a testing ground for theories of the chemical bond since the birth of quantum mechanics a century ago. Understanding the nature of chemical bonding in extreme environments is crucial for expanding our understanding of matter over the broad range of conditions found in the universe.

Observing hydrogen's behavior under very high pressures has been a great challenge for researchers. But recently teams have been able to observe that at pressures of 2-to-3.5 million times normal atmospheric pressure it transforms into an unexpected structure consisting of layered sheets, rather than a close-packed metal as had been predicted many years ago.

These hydrogen sheets resemble the carbon compound graphene. Graphene's layers are each constructed of a honeycomb structure made of six-atom carbon rings. This conventional carbon graphene, first synthesized about a decade ago, is very light, but incredibly strong, and conducts heat and electricity very efficiently. These properties promise revolutionary technology, including advanced optical electronics for screens, high-functioning photovoltaic cells, and enhanced batteries and other energy storage devices.

The new work from Naumov and Hemley shows that the stability of the unusual hydrogen structure arises from the intrinsic stability of its hydrogen rings. These rings form because of so-called aromaticity, which is well understood in carbon-containing molecules such as benzene, as well as in graphene. Aromatic structures take on a ring-like shape that can be thought of as alternating single and double bonded carbons. But what actually happens is that the electrons that make up these theoretically alternating bonds become delocalized and float in a shared circle around the inside of the ring, increasing stability.

Naumov and Hemley's study also indicates that hydrogen initially becomes a dark poorly conducting metal like graphite instead of a conventional shiny metal and a good conductor, as was originally suggested in theoretical calculations going back to the 1930's using early quantum mechanical models for solids.

Though the discovery of this layered sheet character of dense hydrogen has come as a surprise to many, chemists 30 years ago--before the discovery of graphene--predicted the structure based on simple chemical considerations. Their work is validated and extended by the new findings.

"Overall, our results indicate that chemical bonding occurs over a much broader range of conditions than people had previously considered. However, the structural effects of that chemical bonding under extreme conditions can be very different than that observed under the ordinary conditions that are familiar to us," Hemley said.

Source: Carnegie Institution

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Printing in the hobby room: Paper-thin and touch-sensitive displays on various materials

Paper- thin and touch-sensitive displays on various materials.
Credit: Image courtesy of University Saarland

Until now, if you want to print a greeting card for a loved one, you can use colorful graphics, fancy typefaces or special paper to enhance it. But what if you could integrate paper-thin displays into the cards, which could be printed at home and which would be able to depict self-created symbols or even react to touch? Those only some of the options computer scientists in Saarbrücken can offer. They developed an approach that in the future will enable laypeople to print displays in any desired shape on various materials and therefore could change everyday life completely.

For example: A postcard depicts an antique car. If you press a button, the back axle and the steering wheel rim light up in the same color. Two segments on a flexible display, which have the same shape as those parts of the car, can create this effect. Computer scientists working with Jürgen Steimle printed the post card using an off-the-shelf inkjet printer. It is electro-luminescent: If it is connected to electric voltage, it emits light. This effect is also used to light car dashboards at night.

Steimle is leader of the research group "Embodied Interaction" at the Cluster of Excellence "Multimodal Computing and Interaction." Simon Olberding is one of his researchers. "Until now, this was not possible," explains Olberding. "Displays were mass-produced, they were inflexible, they always had a rectangular shape." Olberding and Steimle want to change that. The process they developed works as follows: The user designs a digital template with programs like Microsoft Word or Powerpoint for the display he wants to create.

By using the methods the computer scientists from Saarbrücken developed, called "Screen Printing" and "Conductive Inkjet Printing," the user can print those templates. Both approaches have strengths and weaknesses, but a single person can use them within either a few minutes or two to four hours. The printing results are relatively high-resolution displays with a thickness of only 0.1 millimeters. It costs around €20 to print on a DIN A4 page; the most expensive part is the special ink. Since the method can be used to print on materials like paper, synthetic material, leather, pottery, stone, metal and even wood, two-dimensional and even three-dimensional shapes can be realized. Their depiction can either consist of one segment (surface, shape, pattern, raster graphics), several segments or variously built-up matrixes. "We can even print touch-sensitive displays," says Olberding.

The possibilities for the user are various: displays can be integrated into almost every object in daily life -- users can print not only on paper objects, but also on furniture or decorative accessories, bags or wearable items. For example, the strap of a wristwatch could be upgraded so that it lights up if a text message is received. "If we combine our approach with 3D printing, we can print three-dimensional objects that display information and are touch-sensitive," explains Steimle.

Source: University Saarland

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Mode of action of protein channelrhodopsin-2 decoded: Findings facilitate manufacture of optogenetic tools

The pore of the ion channel is opened by removing the amino acid E90. Water molecules enter and tilt Helix H2, thus opening the continuous channel. Credit: © RUB, graphics: Eisenhauer

Researchers have shed light upon the mode of action of the light-controlled channelrhodopsin-2 with high spatiotemporal resolution. This biomolecule is used in optogenetic applications, which is deployed to control the activity of living cells with light.

"The model we developed makes it possible to create customised optogenetic tools for individual applications," says Prof Dr Klaus Gerwert from the Department of Biophysics at the Ruhr-Universität Bochum. Together with colleagues at the Humboldt Universität zu Berlin from the team headed by Prof Dr Peter Hegemann, the Bochum researchers report about their finding in the magazine "Angewandte Chemie."

Channelrhodopsin-2 has revolutionised optogenetics

Discovered by Peter Hegemann in green algae, channelrhodopsin-2 is the central light-activated channel protein in optogenetics. If this ion channel is applied to nerve cells, the channels can be opened by light, thus activating the cell. "The application of channelrhodopsin-2 in optogenetics has revolutionised neurobiology in the recent years," says Klaus Gerwert. The magazine "Nature Methods" awarded this process as "Method of the Year" in 2010. "However, scientists had not been aware of what is actually happening inside a protein and thus ultimately triggers its activation," continues the Bochum researcher. But it is the understanding of processes on the atomic level that is essential for optimising the protein specifically for its applications.

"EHT" model describes the mode of action of channelrhodopsin-2

With time-resolved vibrational spectroscopy and bio-molecular simulations, the Bochum-Berlin team has now closed that gap. The EHT (E90-Helix2-tilt) model describes the mode of action of channelrhodopsin-2 as follows: the light-sensitive group of the protein, i.e. the retinal, is twistedunder incidence of light. This twist then continues in the protein and opens a pore ultra fast, which is closed by amino acid E90 in the dark. E90 marks the narrowest place in the pore and opens it through a downward move , similar to the motion of a swing door, so that water can enter an empty vestibule above the narrowest place in the pore. The entering water then tilts the protein helix H2, which eventually triggers a protein-traversing open ion channel. When forming this model, the Bochum researchers benefitted from their comprehensive experience that they had gained resolving the mechanism of light-driven proton pump bacteriorhodopsin in detail.

"Protein engineering": pioneering novel optogenetic tools

"With this structural model, the next step, i.e. protein engineering, will become possible," explains Klaus Gerwert. Through mutation of the amino acid E90, the protein's properties can be controlled in a targeted manner. The conductivity or the selectivity for certain ions could be customised for specific applications, and the protein could be specifically activated with different wavelengths.

Source: Ruhr-Universitaet-Bochum

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A new, tunable device for spintronics

Tunable spin Hall angle device based on GaAs through field induced intervalley repopulation.
Credit: Copyright Jairo Sinova

An international team of scientists including physicist Jairo Sinova from the University of Mainz has developed a tunable spin-charge converter made of GaAs.

Spin-charge converters are important devices in spintronics, an electronic which is not only based on the charge of electrons but also on their spin and the spin-related magnetism. Spin-charge converters enable the transformation of electric into magnetic signals and vice versa. Recently, the research group of Professor Jairo Sinova from the Institute of Physics at Johannes Gutenberg University Mainz in collaboration with researchers from the UK, Prague, and Japan, has for the first time realised a new, efficient spin-charge converter based on the common semiconductor material GaAs. Comparable efficiencies had so far only been observed in platinum, a heavy metal. In addition, the physicists demonstrated that the creation or detection efficiency of spin currents is electrically tunable in a certain regime. This is important when it comes to real devices. The underlying mechanism, that was revealed by theoretical works of the Sinova group, opens up a new approach in searching and engineering spintronic materials. These results have recently been published in the journal Nature Materials.

Spintronics does not only make use of the electron's charge to transmit and store information but it takes also advantage of the electron's spin. The spin can be regarded as a rotation of the electron around its own axis, and generates a magnetic field like a small magnet. In some materials, electron spins spontaneously align their direction, leading to the phenomenon of ferromagnetism which is well known e.g. in iron. Additionally, "spin-up" or "spin-down" directions can be used to represent two easily distinguishable states -- 0 and 1 -- used in information technology. This is already used for memory applications such as computer hard discs.

Making use of electron spin for information transmission and storage, enables the development of electronic devices with new functionalities and higher efficiency. To make real use of the electron spin, it has to be manipulated precisely: it has to be aligned, transmitted and detected. The work of Sinova and his colleagues shows, that it is possible to do so using electric fields rather than magnetic ones. Thus, the very efficient, simple and precise mechanisms of charge manipulation well established in semiconductor electronics can be transferred to the world of spintronic and thereby combine semiconductor physics with magnetism.

Spin-charge converters are essential tools for that. They can transform charge currents into spin currents, and vice versa. The main principle behind these converters is the so called spin-Hall effect. Jairo Sinova had already been involved in the prediction and discovery of this relativistic phenomenon in 2004.

The spin-Hall effect appears when an electric field drives electrons through a (semi-) conductor plate. Taking a look at the classical Hall effect that is known from undergraduate physics, the interaction of moving electrons and an external magnetic field forces the electrons to move to one side of the plate, perpendicular to their original direction. This leads to the so called Hall voltage between both sides of the plate. For the spin-Hall effect electron-spins are generated by irradiating the sample with circularly polarised light. The electron spins are then parallel or antiparallel, and their direction is perpendicular to the plate and the direction of movement. The moving electron spins are now forced to one or the other side of the plate, depending on the spin orientation. The driving force behind this is the so called spin-orbit coupling, a relativistic electromagnetic effect which influences moving electron spins. This leads to the separation of both spin orientations.

To make practical use of this effect, it is essential to get a highly efficient spin separation. Up to now, platinum has been the most efficient spin-charge converter material, as it is a heavy metal, and the spin-orbit coupling of heavy metals is known to be especially strong due to the large amount of protons (positive charge) in their core.

Now, Sinova and his colleagues have shown that gallium-arsenide (GaAs), a very common and widely used semiconductor material, can be an as efficient spin-charge converter as platinum, even at room temperature, which is important for practical applications. Moreover, the physicists have demonstrated for the first time that the efficiency can be tuned continuously by varying the electric field that drives the electrons.

The reason for this -- as theoretical calculations of the Sinova group have shown -- lies in the existence of certain valleys in the conduction band of the semiconductor material. One can think of the conduction band and its valleys as of a motor highway with different lanes, each one requiring a certain minimum velocity. Applying a higher electric field enables a transition from one lane to the other.

Since the spin-orbit coupling is different in each lane, a transition also affects the strength of the spin-hall effect. By varying the electric field, the scientists can distribute the electron spins on the different lanes, thus varying the efficiency of their spin-charge converter.

By taking into account the valleys in the conduction band, Sinova and his colleagues open up new ways to find and engineer highly efficient materials for spintronics. Especially, since current semiconductor growth technologies are capable of engineering the energy levels of the valleys and the strength of spin-orbit coupling, e.g. by substituting Ga or As with other materials like Aluminum.

Source: Universität Mainz

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Quantum physics just got less complicated: Wave-particle duality and quantum uncertainty are same thing

Quantum physics says that particles can behave like waves, and vice versa. Researchers have now shown that this 'wave-particle duality' is simply the quantum uncertainty principle in disguise. Credit: Timothy Yeo / CQT, National University of Singapore; CC-BY

Here's a nice surprise: quantum physics is less complicated than we thought. An international team of researchers has proved that two peculiar features of the quantum world previously considered distinct are different manifestations of the same thing. The result is published 19 December in Nature Communications.

Patrick Coles, Jedrzej Kaniewski, and Stephanie Wehner made the breakthrough while at the Centre for Quantum Technologies at the National University of Singapore. They found that 'wave-particle duality' is simply the quantum 'uncertainty principle' in disguise, reducing two mysteries to one.

"The connection between uncertainty and wave-particle duality comes out very naturally when you consider them as questions about what information you can gain about a system. Our result highlights the power of thinking about physics from the perspective of information," says Wehner, who is now an Associate Professor at QuTech at the Delft University of Technology in the Netherlands.

The discovery deepens our understanding of quantum physics and could prompt ideas for new applications of wave-particle duality.

Wave-particle duality is the idea that a quantum object can behave like a wave, but that the wave behaviour disappears if you try to locate the object. It's most simply seen in a double slit experiment, where single particles, electrons, say, are fired one by one at a screen containing two narrow slits. The particles pile up behind the slits not in two heaps as classical objects would, but in a stripy pattern like you'd expect for waves interfering. At least this is what happens until you sneak a look at which slit a particle goes through -- do that and the interference pattern vanishes.

The quantum uncertainty principle is the idea that it's impossible to know certain pairs of things about a quantum particle at once. For example, the more precisely you know the position of an atom, the less precisely you can know the speed with which it's moving. It's a limit on the fundamental knowability of nature, not a statement on measurement skill. The new work shows that how much you can learn about the wave versus the particle behaviour of a system is constrained in exactly the same way.

Wave-particle duality and uncertainty have been fundamental concepts in quantum physics since the early 1900s. "We were guided by a gut feeling, and only a gut feeling, that there should be a connection," says Coles, who is now a Postdoctoral Fellow at the Institute for Quantum Computing in Waterloo, Canada.

It's possible to write equations that capture how much can be learned about pairs of properties that are affected by the uncertainty principle. Coles, Kaniewski and Wehner are experts in a form of such equations known as 'entropic uncertainty relations', and they discovered that all the maths previously used to describe wave-particle duality could be reformulated in terms of these relations.

"It was like we had discovered the 'Rosetta Stone' that connected two different languages," says Coles. "The literature on wave-particle duality was like hieroglyphics that we could now translate into our native tongue. We had several eureka moments when we finally understood what people had done," he says.

Because the entropic uncertainty relations used in their translation have also been used in proving the security of quantum cryptography -- schemes for secure communication using quantum particles -- the researchers suggest the work could help inspire new cryptography protocols.

In earlier papers, Wehner and collaborators found connections between the uncertainty principle and other physics, namely quantum 'non-locality' and the second law of thermodynamics. The tantalising next goal for the researchers is to think about how these pieces fit together and what bigger picture that paints of how nature is constructed.

Source: Centre for Quantum Technologies at the National University of Singapore

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Scientists get to the heart of fool's gold as a solar material

This crystal of iron pyrite shows the characteristic cubic crystals of 'fool's gold.' A new study led by Song Jin at the University of Wisconsin-Madison identifies defects in pyrite's crystal structure as a critical obstacle to building commercial solar cells from the cheap and abundant iron pyrite material. Credit: University of Wisconsin-Madison Geology Museum

As the installation of photovoltaic solar cells continues to accelerate, scientists are looking for inexpensive materials beyond the traditional silicon that can efficiently convert sunlight into electricity.

Theoretically, iron pyrite -- a cheap compound that makes a common mineral known as fool's gold -- could do the job, but when it works at all, the conversion efficiency remains frustratingly low. Now, a University of Wisconsin-Madison research team explains why that is, in a discovery that suggests how improvements in this promising material could lead to inexpensive yet efficient solar cells.

"We think we now understand why pyrite hasn't worked," says chemistry Professor Song Jin, "and that provides the hope, based on our understanding, for figuring out how to make it work. This could be even more difficult, but exciting and rewarding."

Although most commercial photovoltaic cells nowadays are based on silicon, the light-collecting film must be relatively thick and pure, which makes the production process costly and energy-intensive, says Jin.

A film of iron pyrite -- a compound built of iron and sulfur atoms -- could be 1,000 times thinner than silicon and still efficiently absorb sunlight.

Like silicon, iron and sulfur are common elements in Earth's crust, so solar cells made of iron pyrite could have a significant material cost advantage in large scale deployment. In fact, previous research that balanced factors like theoretical efficiency, materials availability, and extraction cost put iron pyrite at the top of the list of candidates for low-cost and large-scale photovoltaic materials.

In the current online edition of the Journal of the American Chemical Society, Jin and first author Miguel Cabán-Acevedo, a chemistry Ph.D. student, together with other scientists at UW-Madison, explain how they identified defects in the body of the iron pyrite material as the source of inefficiency. The research was supported by the U.S. Department of Energy.
In a photovoltaic material, absorption of sunlight creates oppositely charged carriers, called electrons and holes, that must be separated in order for sunlight to be converted to electricity. The efficiency of a photovoltaic solar cell can be judged by three parameters, Jin says, and the solar cells made of pyrite were almost totally deficient in one: voltage. Without a voltage, a cell cannot produce any power, he points out. Yet based on its essential parameters, iron pyrite should be a reasonably good solar material. "We wanted to know, why is the photovoltage so low," Jin says.

"We did a lot of different measurements and studies to look comprehensively at the problem," says Cabán-Acevedo, "and we think we have fully and definitively shown why pyrite, as a solar material, has not been efficient."

In exploring why pyrite was practically unable to make photovoltaic electricity, many researchers have looked at the surface of the crystals, but Cabán-Acevedo and Jin also looked inside. "If you think of this as a body, many have focused on the skin, but we also looked at the heart," says Cabán-Acevedo, "and we think the major problems lie inside, although there are also problems on the skin."

The internal problems, called "bulk defects," occur when a sulfur atom is missing from its expected place in the crystal structure. These defects are intrinsic to the material properties of iron pyrite and are present even in ultra-pure crystals. Their presence in large numbers eventually leads to the lack of photovoltage for solar cells based on iron pyrite crystals.
Science advances by comprehending causes, Jin says. "Our message is that now we understand why pyrite does not work. If you don't understand something, you must try to solve it by trial and error. Once you understand it, you can use rational design to overcome the obstacle. You don't have to stumble around in the dark."

Source: University of Wisconsin-Madison

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Injecting sulfate particles into stratosphere won't fully offset climate change

A polar bear walks along an expanse of open water at the edge of Hudson Bay near Churchill, Manitoba, in 2011. The bears need pack ice to hunt for food, primarily seals, but climate change brings open water more often than it used to. Polar bears have been listed as a threatened species. Credit: Cecilia Bitz, U. of Washington

As the reality and the impact of climate warming have become clearer in the last decade, researchers have looked for possible engineering solutions -- such as removing carbon dioxide from the atmosphere or directing the sun's heat away from Earth -- to help offset rising temperatures.

New University of Washington research demonstrates that one suggested method, injecting sulfate particles into the stratosphere, would likely achieve only part of the desired effect, and could carry serious, if unintended, consequences.

The lower atmosphere already contains tiny sulfate and sea salt particles, called aerosols, that reflect energy from the sun into space. Some have suggested injecting sulfate particles directly into the stratosphere to enhance the effect, and also to reduce the rate of future warming that would result from continued increases in atmospheric carbon dioxide.

But a UW modeling study shows that sulfate particles in the stratosphere will not necessarily offset all the effects of future increases in atmospheric carbon dioxide.

Additionally, there still is likely to be significant warming in regions where climate change impacts originally prompted a desire for geoengineered solutions, said Kelly McCusker, a UW doctoral student in atmospheric sciences.

The modeling study shows that significant changes would still occur because even increased aerosol levels cannot balance changes in atmospheric and oceanic circulation brought on by higher levels of atmospheric carbon dioxide.

"There is no way to keep the climate the way it is now. Later this century, you would not be able to recreate present-day Earth just by adding sulfate aerosols to the atmosphere," McCusker said.
She is lead author of a paper detailing the findings published online in December in the Journal of Climate. Coauthors are UW atmospheric sciences faculty David Battisti and Cecilia Bitz.

Using the National Center for Atmospheric Research's Community Climate System Model version 3 and working at the Texas Advanced Computing Center, the researchers found that there would, in fact, be less overall warming with a combination of increased atmospheric aerosols and increased carbon dioxide than there would be with just increased carbon dioxide.

They also found that injecting sulfate particles into the atmosphere might even suppress temperature increases in the tropics enough to prevent serious food shortages and limit negative impacts on tropical organisms in the coming decades.

But temperature changes in polar regions could still be significant. Increased winter surface temperatures in northern Eurasia could have serious ramifications for Arctic marine mammals not equipped to adapt quickly to climate change. In Antarctic winters, changes in surface winds would also bring changes in ocean circulation with potentially significant consequences for ice sheets in West Antarctica.

Even with geoengineering, there still could be climate emergencies -- such as melting ice sheets or loss of polar bear habitat -- in the polar regions, the scientists concluded. They added that the odds of a "climate surprise" would be high because the uncertainties about the effects of geoengineering would be added to existing uncertainties about climate change.

The research was funded by the Tamaki Foundation and the National Science Foundation.

Source: University of Washington

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