New method for detecting water on Mars

Washington State University senior Kellie Wall has helped develop a new method for detecting water on Mars. Her findings appear in Nature Communications, one of the most influential general science journals. Credit: Washington State University photo

A Washington State University undergraduate has helped develop a new method for detecting water on Mars.  

Kellie Wall, 21, of Port Orchard, Wash., looked for evidence that water influenced crystal formation in basalt, the dark volcanic rock that covers most of eastern Washington and Oregon. She then compared this with volcanic rock observations made by the rover Curiosity on Mars' Gale Crater.

"This is really cool because it could potentially be useful for not only the study of rocks on Earth but on Mars and other planets," said Wall.

She is the lead author of the article in Nature Communications.  

Co-authors include Michael Rowe, a former WSU research professor now at New Zealand's University of Auckland, and Ben Ellis, a former WSU post-doctoral researcher now at the Institute of Geochemistry and Petrology in Zurich, Switzerland. The other authors are Mariek Schmidt of Brock University in Canada and Jennifer Eccles of the University of Auckland.

Wall was fascinated by volcanoes as a child, touring the Cascade mountain range with her father and marveling at features like the lava tubes under Mount St. Helens.

"I was really excited because I thought that just on the other side of the walls there could be lava," she said.

Still, she started out as a communications major at WSU, choosing a geology class to fulfill a science requirement.

"I loved it so much that I changed my major," she said.

In her sophomore year, Rowe and Ellis asked if she would like to look at the eruption styles of Earth and Mars volcanoes.

"I was really crazy about it -- really intrigued by the buzzword 'Mars,'" she said.

"I've worked with a lot of undergraduate researchers over the years and she's the best that I've come across," said Rowe. "That's why we gave her so much responsibility on this project, because we knew she would do it well."

The researchers established a method to quantify the texture of volcanic rock using an index called "groundmass crystallinity." Wall compares it to the texture of a chocolate chip cookie, which can vary according to how it is cooked and cooled.

"We were interested in the cookie dough part of the cookie," she said.

Liquid volcanic rock cools rapidly as it hits water, flash-freezing to form mostly glass. Without water, it takes longer to cool and forms crystals within the groundmass, the cookie dough part.

Using an x-ray diffraction machine on the WSU campus, home to one of the most sophisticated basalt labs in the world, Wall analyzed rock samples from the Northwest, New Zealand and Italy's Mount Etna and compared them to rocks analyzed by Curiosity's x-ray diffractometer.

"The rocks that erupted and interacted with water, which we call phreatomagmatic, all had a groundmass crystallinity as low as 8 percent and ranging up to about 35 percent," she said. 

"The rocks that erupted without interaction with water had groundmass crystallinities from about 45 percent upwards to almost totally crystalline.

"The analyses we did on the Mars soil samples fell in the range of the magmatic type eruptions, which are the ones erupted without water interaction," she said.

Water is a key indicator for the potential of microbial life on the red planet. While Wall and her colleagues didn't see evidence of it from two sites they studied, their method could look for water elsewhere.

"I think this quantification of volcanic textures is a new facet of the water story that hasn't yet been explored," Wall said. "Most of the studies searching for water have focused on either looking for sedimentary structures -- large- and small-scale -- for evidence of water, or looking for rocks like limestones that actually would have formed in a water-rich environment.

"But being able to determine the environment through the texture of a volcanic rock is something pretty cool and different," she said. "I think it's an interesting avenue for future research."

Source: Washington State University

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Put a plastic bag in your tank: Converting polyethylene waste into liquid fuel

Researchers in India have developed a relatively low-temperature process to convert certain kinds of plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products.

Researchers in India have developed a relatively low-temperature process to convert certain kinds of plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products. They report full details next month in the International Journal of Environment and Waste Management.

Many pundits describe the present time as the "plastic age" for good reason and as such we generate a lot plastic waste. Among that waste is the common polymer, low-density polyethylene (LDPE), which is used to make many types of container, medical and laboratory equipment, computer components and, of course, plastic bags. Recycling initiatives are in place in many parts of the world, but much of the polyethylene waste ends up in landfill, dispersed in the environment or in the sea.

Chemist Achyut Kumar Panda of Centurion University of Technology and Management Odisha, India is working with chemical engineer Raghubansh Kumar Singh of the National Institute of Technology, Orissa, India, to develop a commercially viable technology for efficiently rendering LDPE into a liquid fuel. Given that most plastics are made from petrochemicals, this solution to plastic recycling brings the life-cycle full circle allowing a second use as an oil substitute. The process could, if implemented on a large enough scale, reduce pressures on landfill as well as ameliorating the effects of dwindling oil supplies in a world with increasing demands on petrochemicals for fuel.

In their approach, the team heats the plastic waste to between 400 and 500 Celsius over a kaolin catalyst. This causes the plastic's long chain polymer chains to break apart in a process known as thermo-catalytic degradation. This releases large quantities of much smaller, carbon-rich molecules. The team used the analytical technique of gas chromatography coupled mass spectrometry to characterize these product molecules and found the components of their liquid fuel to be mainly paraffins and olefins 10 to 16 carbon atoms long. This, they explain, makes the liquid fuel very similar chemically to conventional petrochemical fuels.

In terms of the catalyst, Kaolin is a clay mineral -- containing aluminum and silicon. It acts as a catalyst by providing a large reactive surface on which the polymer molecules can sit and so be exposed to high temperature inside the batch reactor, which breaks them apart. The team optimized the reaction at 450 Celsius a temperature with the lowest amount of kaolin at which more than 70% of the liquid fuel is produced. In other words, for every kilogram of waste plastic they could produce 700 grams of liquid fuel. The byproducts were combustible gases and wax. They could boost the yield to almost 80% and minimize reaction times, but this required a lot more catalyst 1 kg of kaolin for every 2 kg of plastic.

Source: Inderscience Publishers

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